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Progress in Chemistry 2008, Vol. 20 Issue (12): 1886-1895 Previous Articles   Next Articles

• Review •

The Sharpless Epoxidation of Molybdenum Peroxide and Tungsten Peroxide

Jin Fei; Ding Hangjun; Luan Yi; Wang Ge

  

  1. ( University of Science and Technology Beijing, Beijing 100083, China)
  • Received: Revised: Online: Published:
  • Contact: Wang Ge
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Peroxo molybdenum and tungsten complexes are very important catalysts in the Sharpless olefins epoxidation, which are potential materials for the catalytic industrialization. The types, structures, synthesis and applications of peroxo Molybdenum and Tungsten complexes are reviewed in this article. The characteristics and recent development in epoxidation are also discussed. On the other hand, the epoxidation mechanism is discussed. The argument and recent development of two epoxidation theories——Mimoun Mechanism and Sharpless Mechanism are reviewed, the recent research progress of calculated chemistry for the transition structure is discussed, and the transition structure of Sharpless Mechanism is mainly discussed. The factors which may affect the catalytic activity are summarized, and the side reactions caused by proton are reviewed. Finally, suggestions for further research of epoxidation are proposed.
Key words: molybdenum peroxide, tungsten peroxide, epoxidation, Sharpless mchanism

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