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Progress in Chemistry 2008, Vol. 20 Issue (11): 1733-1739 Previous Articles   Next Articles

• Review •

Development of Research on Ladderlike Polysiloxane Liquid Crystalline

  

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Abstract The ladderlike polysiloxane liquid crystalline was a novel functional material with many excellent and special properties, such as stability, transparency and film forming characteristic. In this paper, the main advances in the research of the ladderlike polysiloxane liquid crystalline in recent years were reviewed. The structural characteristics were particularly introduced. Then according to the different ways of mesogenic units connecting to the ladderlike main-chain, the ladderlike polysiloxane liquid crystalline was classified into fishbonelike and conoelike. The synthesis of ladderlike polysiloxanes with different side-groups was summarized. These kinds of ladderlike polysiloxane contained ladderlike polyphenylsiloxane, ladderlike polymethylsiloxane, ladderlike polyhydrosiloxane, ladderlike polyvinylsiloxane, and so on. Then the synthesis of ladderlike polysiloxane liquid crystalline with different mesogenic units was introduced. At last, the difficulties of research on ladderlike polysiloxane were mentioned, and its development prospect was looked forward.
Key words: liquid crystalline polymer, ladderlike polysiloxane, classification, synthesis

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