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Progress in Chemistry 2008, Vol. 20 Issue (11): 1726-1732 Previous Articles   Next Articles

• Review •

Recent Developments of the Initiation System of Atom Transfer Radical Polymerizatio

  

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Novel methods of fine tuning initiation, activation, and deactivation processes for atom transfer radical polymerization (ATRP) are reviewed, including reverse ATRP, simultaneous reverse and normal initiation (SR&NI) ATRP, activators generated by electron transfer (AGET) ATRP, activators regenerated by electron transfer (ARGET) ATRP and initiators for continuous activator regeneration (ICAR) ATRP, which gradually overcome the limitations of normal ATRP methods, especially the latter two methods whereby only small amount of high-oxidation-state transition metal complex is needed to mediate polymerization and therefore greatly simplify the commercial procedures. In addition, two novel catalyst systems, hybrid and bimetallic catalyst systems developed on the basis of immobilized catalyst, are thoroughly introduced, which show high catalytic activity and control capability to polymerization and can be removed mostly by simple filtration or precipitation.
Key words: atom transfer radical polymerization, initiation, activation and deactivation process, metallic catalyst system

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[1 ] Farcet C,Lansalot M,Charleux B,etal.Macromolecules,2000 ,33(23) :8559 —8570
[2 ] Chiefari J,Chong Y K,Ercole F,etal.Macromolecules,1998 ,31(16) :5559 —5562
[3 ] Wang J S,Matyjaszewski K.J.Am.Chem.Soc.,1995 ,117(20) :5614 —5615
[4 ] Wang J S,Matyjaszewski K.Macromolecules,1995 ,28 (23) :7901 —7910
[5 ] Kato M,Kamigaito M,Sawamoto M,etal.Macromolecules,1995 ,28 (5) :1721 —1723
[6 ] Matyjaszewski K,Xia J H.Chem.Rev.,2001 ,101 (9) :2921 —2990
[7 ] Matyjaszewski K,Paik H J,Zhou P,etal.Macromolecules,2001 ,34 (15) :5125 —5131
[8 ] Matyjaszewski K,Patten T E,Xia J H.J.Am.Chem.Soc.,1997 ,119 (4) :674 —680
[9 ] Qiu J,Matyjaszewski K.Macromolecules,1997 ,30 ( 19 ) :5643 —5648
[10 ] Grimaud T,Matyjaszewski K.Macromolecules,1997 ,30 (7) :2216 —2218
[11 ] Matyjaszewski K,Thomas G.Polym.Prep. (Am.Chem.Soc.,Div.Polym.Chem. ) ,1997 ,38 (1) :456 —457
[12 ] Matyjaszewski K,Jo S M,Paik H J,etal.Macromolecules,1997 ,30 (20) :6398 —6400
[13 ] Teodorescu M,Matyjaszewski K.Macromolecules,1999 ,32(15) :4826 —4831
[14 ] Coessens V,Pintauer T,Matyjaszewski K.Prog.Polym.Sci.,2001 ,26 (3) :337 —377
[15 ] Tsarevsky N V,Matyjaszewski K.Macromolecules,2002 ,35(24) :9009 —9014
[16 ] Marsh A,Khan A,Haddleton D M,etal.Macromolecules,1999 ,32 (26) :8725 —8731
[17 ] Ashford E J,Naldi V,O'Dell R,etal.Chem.Commun.,1999 ,14:1285 —1286
[18 ] Wang X S,Jackson R A,Armes S P.Macromolecules,2000 ,33(2) :255 —257
[19 ] Liu S,Armes S P.J.Am.Chem.Soc.,2001 ,123 ( 40) :9910 —9911
[20 ] Liu S,Weaver JVM,Tang Y,etal.Macromolecules,2002 ,35(16) :6121 —6131
[21 ] Liu S,Armes S P.Langmuir,2003 ,19 (10) :4432 —4438
[22 ] Weaver J V M,Bannister I,Robinson K L,etal.Macromolecules,2004 ,37 (7) :2395 —2403
[23 ] Zhang W,Shi L,GaoL,etal.Macromolecules,2005 ,38 (3) :899 —903
[24 ] AminA.J.Macromol.Sci.Part A -PureAppl.Chem.,2007 ,44(3) :329 —335
[25 ] Ana C C E,Lindsay B,TitoT,etal.Small,2007 ,3 ( 7) :1230 —1236
[26 ] Min K,Yu S,Lee H I,etal.Macromolecules,2007 ,40 (18) :6557 —6563
[27 ] Xia J H,GaynorS G,Matyjaszewski K.Macromolecules,1998 ,31(17) :5958 —5959
[28 ] Qiu J,Matyjaszewski K,ThouinL,etal.Macromol.Chem.Phys.,2000 ,201 (14) :1625 —1631
[29 ] Wang J S,Matyjaszewski K.Macromolecules,1995 ,28 (22) :7572 —7573
[30 ] Hou C,Qu R J,Ji C N,etal.Polym.Int.,2006 ,55 (3) :326 —329
[31 ] Roland A M,McKnight J N,Sarry L R,etal.Abstr.Pap.Am.Chem.Soc.,2005 ,230:art.no.U844
[32 ] AydoganB,YagciYT.J.Chem.,2007 ,31 (1) :1 —10
[33 ] Li N J,Lu J M,Xu Q F,etal.J.Appl.Polym.Sci.,2007 ,103(6) :3915 —3919
[34 ] Feng H,Dan Y.J.Appl.Polym.Sci.,2006 ,99 (3) :1093 —1099
[35 ] Hou C,Ji C,Qu R,etal.J.Appl.Polym.Sci.,2007 ,105(3) :1575 —1580
[36 ] Gromada J,Matyjaszewski K.Macromolecules,2001 ,34 (22) :7664 —7671
[37 ] Gromada J,Cooper B M,Matyjaszewski K.Abstr.Pap.Am.Chem.Soc.,2002 ,224:art.no.U439
[38 ] Min K E,Jahed N M,Matyjaszewski K,etal.Polym.Prep.(Am.Chem.Soc.,Div.Polym.Chem. ) ,2004 ,45 (2) :682 —683
[39 ] Li M,Jahed N M,Min K,etal.Macromolecules,2004 ,37 (7) :2434 —2441
[40 ] Min K E,Li M,Matyjaszewski K.J.Polym.Sci.PartA:Polym.Chem.,2005 ,43 (16) :3616 —3622
[41 ] Li M,Min K,Matyjaszewski K.Macromolecules,2004 ,37 (6) :2106 —2112
[42 ] Matyjaszewski K,Coca S,Gaynor S G,etal.Macromolecules,1997 ,30 (23) :7348 —7350
[43 ] DeVries A,Klumperman B,deWet-Roos D,etal.Macromol.Chem.Phys.,2001 ,202 (9) :1645 —1648
[44 ] Jakubowski W,Matyjaszewski K.Macromolecules,2005 ,38(10) :4139 —4146
[45 ] Ke M,Haifeng G,Matyjaszewski K.J.Am.Chem.Soc.,2005 ,127 (11) :3825 —3830
[46 ] Tang H,Radosz M,Shen Y.Macromol.Rapid Commun.,2006 ,27(14) :1127 —1131
[47 ] Matyjaszewski K,Coca S,Gaynor S G,etal.Macromolecules,1998 ,31 (17) :5967 —5969
[48 ] Gnanou Y,Hizal G.J.Polym.Sci.PartA:Polym.Chem.,2003 ,42 (2) :351 —359
[49 ] Hizal G,Tunca U,Aras S,etal.J.Polym.Sci.PartA: Polym.Chem.,2005 ,44 (1) :77 —87
[50 ] Min K,Gao H,Matyjaszewski K.J.Am.Chem.Soc.,2005 ,127(11) :3825 —3830
[51 ] Oh J K,Perineau F,Matyjaszewski K.Macromolecules,2006 ,39(23) :8003 —8010
[52 ] Oh J K,Perineau F,Matyjaszewski K.Polym.Prep. ( Am.Chem.Soc.,Div.Polym.Chem. ) ,2006 ,47 (2) :464 —465
[53 ] Min K,Jakubowski W,Matyjaszewski K.Macromol.Rapid Commun.,2006 ,27 (8) :594 —598
[54 ] Esteves A C C,Bombalski L,Cusick B,etal.Polym.Prep.(Am.Chem.Soc.,Div.Polym.Chem. ) ,2005 ,46 ( 2) :134 —135
[55 ] Min K,Yu S,Lee H I,etal.Macromolecules,2007 ,40 (18) :6557 —6563
[56 ] Mueller L,Jakubowski W,Tang W,etal.Macromolecules,2007 ,40 (18) :6464 —6472
[57 ] Matyjaszewski K.Nanostructured Functional Polymers Preparedby ATRP with ppm Amountsof Cu.233rd ACS National Meeting,Chicago,2007.25 —29
[58 ] Braunecker W A,Matyjaszewski K.Prog.Polym.Sci.,2007 ,32(1) :93 —146
[59 ] Matyjaszewski K,Jakubowski W,Min K,etal.Proc.Natl.Acad.Sci.USA,2006 ,103 (42) :15309 —15314
[60 ] Jakubowski W,Min K.Macromolecules,2006 ,39 (1) :39 —45
[61 ] Jakubowski W,Kirci-Denizli B,Gil R R,etal.Macromol.Chem.Phys.,2007 ,16 (9) :775 —777
[62 ] Min K,Gao H,MatyjaszewskiK.Macromolecules,2007 ,40(6) :1789 —1791
[63 ] Pietrasik J,Dong H C,MatyjaszewskiK.Macromolecules,2006 ,39(19) :6384 —6390
[64 ] Dong H C,Tang W,Matyjaszewski K.Macromolecules,2007 ,40(9) :2974 —2977
[65 ] Jakubowski W,Matyjaszewski K.Angew.Chem.Int.Ed.,2006 ,45 (27) :4482 —4486
[66 ] Kickelbick G,Paik H J,MatyjaszewskiK.Macromolecules,1999 ,32 (9) :2941 —2947
[67 ] Shen Y Q,Zhu S P,Pelton R.Macromol.Rapid Commun.,2000 ,21 (14) :956 —959
[68 ] Shen Y Q,Zhu S P,Zeng F Q,etal.Macromolecules,2000 ,33(15) :5427 —5431
[69 ] Hong S C,Paik H J,Matyjaszewski K.Macromolecules,2001 ,34(15) :5099 —5102
[70 ] Faucher S,Zhu S P.Macromolecules,2006 ,39 (14) :4690 —4695
[71 ] Inoue Y,Matyjaszewski K.Macromolecules,2003 ,36 ( 20) :7432 —7438
[72 ] Hong S C,Matyjaszewski K.Macromolecules,2002 ,35 (20) :7592 —7605.
[73 ] Tsarevsky N V,Pintauer T,Matyjaszewski K.Macromolecules,2004 ,37 (26) :9768 —9778
[74 ] Gobelt B,Matyjaszewski K.Macromol.Chem.Phys.,2000 ,201(14) :1619 —1624
[75 ] Gillies M B,Matyjaszewski K,Norrby P O,etal.Macromolecules,2003 ,36 (22) :8551 —8559
[76 ] Tang W,MatyjaszewskiK.Polym.Prep. (Am.Chem.Soc.,Div.Polym.Chem. ) ,2005 ,46 (2) :211 —212
[77 ] Nanda A K,Matyjaszewski K.Macromolecules,2003 ,36 (3) :599 —604
[78 ] Nanda A K,Matyjaszewski K.Macromolecules,2003 ,36 (5) :1487 —1493
[79 ] Matyjaszewski K,Nanda A K,Tang W.Macromolecules,2005 ,38(5) :2015 —2018
[80 ] Tang W,Nanda A K,MatyjaszewskiK.Macromolecular Chemistry and Physics,2005 ,206 (12) :1171 —1177
[81 ] Nanda A K,Matyjaszewski K.Macromolecules,2003 ,36 (22) :8222 —8224
[82 ] Pintauer T,Matyjaszewski K.Coord.Chem.Rev.2005 ,249(11/12) :1155 —1184
[83 ] Matyjaszewski K.Macromol.Symp.,1998 ,134:105 —118
[84 ] Qiu J,Matyjaszewski K.Acta Polym.,1997 ,48 (5/6) :169 —180
[85 ] Haddleton D M,Shooter A J,Hannon M J,etal.Polym.Prep.(Am.Chem.Soc.,Div.Polym.Chem. ) ,1997 ,38 ( 1) :679 —680
[86 ] Braunecker W A,PintauerT,TsarevskyNV,etal.J.Organomet.Chem.,2005 ,690 (4) :916 —924
[87 ] Braunecker W A,Tsarevsky N V,PintauerT,etal.Mac-romolecules,2005 ,38 (10) :4081 —4088
[88 ] LeGrognec E,Claverie J,Poli R.J.Am.Chem.Soc.,2001 ,123(39) :9513 —9524
[89 ] Gibson V C,O'Reilly R K,Rzepa H S,etal.Prep. (Am.Chem.Soc.,Div.Polym.Chem. ) ,2005 ,46 (2) :160 —161
[90 ] Bednarek M,Biedron T,Kubisa P.Macromol.Chem.Phys.,2000 ,201 (1) :58 —66
[91 ] Schoen F,Hartenstein M,Mueller A H E.Macromolecules,2001 ,34 (16) :5394 —5397
[92 ] Huang J,Pintauer T,Matyjaszewski K.J.Polym.Sci.Part A: Polym.Chem.,2004 ,42 (13) :3285 —3292
[93 ] Lutz J F,Matyjaszewski K.Macromol.Chem.Phys.,2002 ,203(10/11) :1385 —1395
[94 ] Lutz J F,Matyjaszewski K.J.Polym.Sci.PartA:Polym.Chem.,2005 ,43 (4) :897 —910
[95 ] Tsarevsky N V,Pintauer T,Matyjaszewski K.Polym.Prep.(Am.Chem.Soc.,Div.Polym.Chem. ) ,2002 ,43 ( 2) :203 —204
[96 ] Pintauer T,Reinoehl U,Feth M,etal.Eur.J.Inorg.Chem.,2003 , (11) :2082 —2094
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