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Progress in Chemistry 2008, Vol. 20 Issue (11): 1694-1698 Previous Articles   Next Articles

• Review •

The Application of Cyclodextrins in Greeen Organic Synthesis

Ai-You Hao Zhang Hua-Cheng Jian Shen   

  • Received: Revised: Online: Published:
  • Contact: Ai-You Hao
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Cyclodextrins, widely applied in green organic synthesis, could transfer hydrophobic molecules into water by the supramolecular interaction. As an important kind of host molecules, they could also influence the microenviroment of hydrophobic molecules by the host-guest interaction and change traditional reaction conditions to obtain good yield without byproduct. The recent developments of appliacation of cycodextrins in green organic reactions such as oxidation reaction, addition reaction, ring opening reaction, deprotection reaction, coupling reaction, substitution reaction, et al were reviewed. The catalytic mechanisms were also discussed in this manuscript.

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[1 ] Anastas P T,Warner T C.Green Chemistry: Theoryand Practice.London: Oxford Science Publication,1998 .1 —30
[2 ] 童林荟( Tong L H ) . 环糊精化学———基础与应用(Cydodextrins Chemistry: Basicand Application) . 北京: 科学出版社(Beijing:Science Press ) ,2001 .10 —12
[3 ] Frigerio M,Santagostino M.Tetrahedron Lett.,1994 ,35 (43) :8019 —8022
[4 ] Frigerio M,Santagostino M,Sputore S.J.Org.Chem.,1995 ,60 (22) :7272 —7276
[5 ] Surendra K,Krishnaveni N S,Reddy M A,etal.J.Org.Chem.,2003 ,68:2058 —2059
[6 ] Frigerio M,Santagostino M,Sputore S.J.Org.Chem.,1999 ,64:4537 —4538
[7 ] Surendra K,Krishnaveni N S,Reddy M A,etal.J.Org.Chem.,2003 ,68:9119 —9121
[8 ] Ji H B,Shi D P,Shao M,etal.Tetrahedron Letters,2005 ,46:2517 —2520
[9 ] Surendra K,Krishnaven N S,Kumar V P,etal.Tetrahedron Letters,2005 ,46:4581 —4583
[10 ] Rossi L I,deRossi R H.Applied Catalysis A:General,2004 ,267:267 —272
[11 ] 邓芳(Deng F) , 兰支利(Lan Z L ) , 尹笃林( Yin D L ) , 肖自胜(Xiao Z S ) . 化学通报( Chemistry Online ) ,2006 , ( 5 ) :362 —365
[12 ] Zolezzi S,podine E S,Decinti A.Polyhedron,2003 ,22:1653 —16581
[13 ] Frunza L,Kosslick H,Landmesser H.J.Mol.Catal.A: Chem.,1997 ,123:179 —187
[14 ] Surendra K,Krishnaveni N S,Sridhar R,etal.J.Org.Chem.,2006 ,71:5819 —5821
[15 ] Nishikido J,Nanbo M,Yoshida A,etal.Synlett,2002 , (10) :1613 —1616
[16 ] Imperato G,Eibler E,Niedermaier J,etal.Chem.Commun.,2005 ,1170 —1172
[17 ] Narender M,Reddy M S,Sridhar R,etal.Tetrahedron Letters,2005 ,46:5953 —5955
[18 ] Shilpa C M,Kumaranand P,Muralidhara T,etal.Chem.Commun.,2005 ,3207 —3209
[19 ] Krishnaveni N S,Surendra K,Rao K R.Chem.Commun.,2005:669 —671
[20 ] Surendra K,Krishnaveni N S,Sridhar R,etal.Tetrahedron Letters,2006 ,47:2125 —2127
[21 ] Krishnaveni N S,Surendra K,Kumar V P,etal.Tetrahedron Letters,2005 ,46:4299 —4301
[22 ] Islami M R,Yavari I,Tikdari A M,etal.Russian Chemical Bulletin,International Edition,2002 ,51 (12) :2244 —2247
[23 ] Movassagh B,Shamsipoor M.Synlett,2005 :1316 —1318
[24 ] Barros O Sdo R,deCarvalho A B,Lang E S,Peppe C.Lett.Org.Chem.,2004 ,1:43 —46;
[25 ] Surendra K,Krishnaveni N S,Rao K R.J.Org.Chem.,2003 ,68:4994 —4995
[26 ] Reddy M S,Srinivas B,Rao K R,etal.Journal of Molecular Catalysis A: Chemical,2006 ,255:180 —183
[27 ] Surendra K,Krishnaveni N S,Rao K R.Synlett,2005 ,506 —510
[28 ] Surendra K,Krishnaveni N S,Rao K R.J.Org.Chem.,2006 ,71:5819 —5821
[29 ] Sridhar R,Srinivas B,Rao K R,etal.Tetrahedron Letters,2005 ,46:8837 —8839
[30 ] Reddy M A,Surendra K,Bhanumathi N,Rao K R,etal.Tetrohedron,2002 ,58:6003 —6008
[31 ] Srinivas B,Kumar V P,Rao K R,etal.Journal of Molecular Catalysis A: Chemical,2007 ,261:1 —5
[32 ] Sabitha G,Babu R S,Rajkumar M,etal.Tetrahedron Letters,2001 ,42:3955 —3958
[33 ] Yadav J S,Subba Reddy B V,Mahesh K G.Synlett,2001 :1417 —1418
[34 ] Reddy M S,Narender M,Rao K R.Synlett,2005 ,489 —490
[35 ] Krishnaveni N S,Surendra K,Rao K R,etal.Synthesis,2004 ,501 —502
[36 ] Krishnaveni N S,Surendra K,Rao K R.Adv.Synth.Catal.,2006 ,348:696 —700
[37 ] Krishnaveni N S,Surendra K,Nageswar Y V D,etal.Synthesis,2003 ,13:1968 —1970
[38 ] Krishnaveni N S,Surendra K,Nageswar Y V D,etal.Synthesis,2003 ,15:2295 —2297
[39 ] Ji H B.Eur.J.Org.Chem.,2003 ,3659 —3662
[40 ] Francesco T,Glancarlo C,Stefano R.Journl of Inclusion Phenomal and Macrocyclic Chemistry,2002 ,44:293 —296
[41 ] Yadav J S,Reddy B V S,Baishya G.Synlett,2003 ,396 —398
[42 ] Tamami B,Kolahdoozan M.Tetrahedron Letters,2004 ,45:1535 —1537
[43 ] Kaboudin B,Norouzi H.Tetrahedron Letters,2004 ,45:1283 —1285
[44 ] Yadav J S,Reddy B V S,Reddy Ch S,Rajasekhar K.J.Org.Chem.,2003 ,68:2525 —2527
[45 ] Surendra K,Krishnaveni N S,Rao K R.Tetrahedron Letters,2004 ,45:6523 —6526

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[4] Liu Li Wang Dong. Organic Reactions "on Water" [J]. Progress in Chemistry, 2010, 22(07): 1233-1241.
[5] . Cyclodextrin-Containing Supramolecular Hydrogels [J]. Progress in Chemistry, 2010, 22(05): 916-926.
[6] . Application of Cyclodextrins in Polymerization [J]. Progress in Chemistry, 2010, 22(05): 927-937.
[7] . Theoretical Calculation of Cyclodextrins [J]. Progress in Chemistry, 2010, 22(05): 803-811.
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[9] Bo Jing,Xiao Chen**,Yongcun Chai. Assembling Poly(pseudo)rotaxanes from Cyclodextrins and Macromolecules [J]. Progress in Chemistry, 2006, 18(10): 1361-1368.
[10] Linhui Tong Runhua Lu Yoshihisa Inoue Inoue . Asymmetric Photochemistry with Native and Modified Cyclodextrins [J]. Progress in Chemistry, 2006, 18(05): 533-541.