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Progress in Chemistry 2008, Vol. 20 Issue (11): 1635-1641   Next Articles

• Review •

Mechanism of Selective Oxidations of Hydrocarbons with Hydrogen Peroxide Catalyzed by Metalloporphyrins

  

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Recent researches on mechanism of hydrocarbon selective oxidations with hydrogen peroxide catalyzed by metalloporphyrins including iron porphyrins and manganese porphyrins are reviewed in this paper. The strategies to promote heterolytic cleavage of hydrogen peroxide to facilitate the formation of active high valent metal-oxo species were discussed in details.
Key words: iron porphyrins, manganese porphyrins, selective oxidation, selective oxidation, hydrogen peroxide

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