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Progress in Chemistry 2008, Vol. 20 Issue (10): 1578-1587 Previous Articles   Next Articles

• Review •

Star-shaped Polylactic Acid

Luo Yufen; Wang Zhaoyang**; Song Xiumei; Mao Zhengzhou   

  1. （Department of Chemistry, South China Normal University, Guangzhou 510006, China）
  • Received: Revised: Online: Published:
  • Contact: Wang Zhaoyang
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The star-shaped polylactic acid (SPLA) have received considerable attention due to their unique structure and good properties. Usually, SPLA are synthesized by the “core first” method., which classified by different “core” in SPLA, such as small molecular polyol (including natural sugar alcohols), hydroxyl-terminated (cyclotri)phosphazene derivatives, hydroxyl-terminated metallic organic compounds, hydroxyl-terminated phenolic derivatives, and some star-shaped macroinitiator. The progress on their synthesis, especially via the ring-opening polymerization of lactide, properties and application are summarized. It is pointed out that the higher mulecular weight and lower viscosity, better solubility and thermal properties made SPLA have more application in biomedical material (including drug delivery carrier) than linear polylactic acid (LPLA).
Key words: star-shaped polylactic acids, initiators, core, synthesis

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Abstract

Star-shaped Polylactic Acid