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Progress in Chemistry 2008, Vol. 20 Issue (10): 1572-1577 Previous Articles   Next Articles

• Review •

Living Radical Polymerization of N-vinylamides

Pu Hongting1 Cai Xiangyu1 Wan Decheng1** Yang Genjin2   

  1. (1. Institute of Functional Polymers, School of Materials Science & Engineering, Tongji University, Shanghai 200092, China;2. School of Pharmacy, The Second Military Medical University, Shanghai 200433, China)
  • Received: Revised: Online: Published:
  • Contact: Wan Decheng
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The progress regarding the living radical polymerization of N-vinylamides(NVAs) is summarized. The living radical polymerization of the unconjugated NVAs once represented a synthetic challenge, but pleasant progress has been made recently in this field. It is found that selected members of the xanthate family and dithiocarbamate family are able to control the polymerization of NVAs via reversible addition-fragmentation chain transfer (RAFT) polymerization or via the interchange of xanthate (MADIX) under certain conditions, and the tacticity can be simultaneously controlled under specific conditions. The recently developed organobismuth, organostibine and organotellurium compounds are effective mediators for the (co) polymerization of most NVAs, expanding the spectra of polymer composition. Additionally, some of the atom transfer radical polymerization (ATRP) systems are applicable to the polymerization of NVAs.
Key words: N-vinylamide, living radical polymerization, organobismuth, organostibine, organotellurium

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