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Progress in Chemistry 2008, Vol. 20 Issue (10): 1553-1561 Previous Articles   Next Articles

• Review •

Hydrogen Production from Organic Compounds by Supercritical Water Gasification

Yan Bo1,2 Wei Chaohai2**   

  1. (1. Guangzhou Institute of Geochemistry, Chinese Acadeniy of Sciences, Guangzhou 510640, China; 2. College of Environmental Science and Engineering, South China University of Technology, Guangzhou, 510006, China)
  • Received: Revised: Online: Published:
  • Contact: Wei Chaohai
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Hydrogen can be obtained from organic compounds by Supercritical Water Gasification (SCWG). In this paper, the influence factors, intermediates and reaction pathway of glucose, methanol, cellulose, lignin, real biomass and organic waste/wastewater by SCWG are summarized. The effect of catalyst such as alkali metals, ZrO2, activated carbon, noble and transition metal on gasification efficiency and gasification mechanism is illustrated and which is suggested that the study of heterogeneous catalytic reaction is very important for the development of SCWG. The thermodynamics of SCWG is analysed, the difficulty for scale-up of SCWG is discussed and three pilot-scale SCWG units in the world are introduced. The research trends in SCWG are proposed.
Key words: supercritical water, gasification, hydrogen production, catalysis

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