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Progress in Chemistry 2008, Vol. 20 Issue (10): 1515-1524 Previous Articles   Next Articles

• Review •

Cationic Complexes of Rare Earth Metals

Yu Nan1,2 Hou Zhaomin2** Xi Zhenfeng1**

  

  1. (1. College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China; 2. Organometallic Chemistry Laboratory, the Institute of Physical and Chemical Research, Japan)
  • Received: Revised: Online: Published:
  • Contact: Xi Zhenfeng
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The cationic complexes of transition metals serve as catalytically active species for olefin polymerization. Their structures and properties directly influence the resulting polymers in terms of microstructure and function. The intensive investigation about cationic alkyl complexes of group 4 metals has recently prompted interest in cationic early transition metal complexes and rare earth metal complexes. In contrast to the large number of neutral and anionic complexes of rare earth metals, the cationic complexes have remained scarce until recently due to their high reactivity and synthetic difficulties. This review summarizes the recent progress in the synthesis, structural characterization and olefin polymerization catalysis of these cationic complexes of rare earth metals.
Key words: cationic complexes, rare earth metals, synthesis, structure, olefin polymerization catalysis

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Abstract

Cationic Complexes of Rare Earth Metals