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Progress in Chemistry 2008, Vol. 20 Issue (10): 1447-1452   Next Articles

• Review •

Application of In Situ FTIR to Deactivation by Coke Deposition

Zhu Ning; Wang Yang; Chen Fengqiu**; Zhan Xiaoli   

  1. (UNILAB Research Center for Chemical Reaction Engineering, Zhejiang University, Hangzhou 310027, China)
  • Received: Revised: Online: Published:
  • Contact: Chen Fengqiu
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The advantages of in-situ Fourier transform infrared (FTIR) spectrometry to coke deposition during catalytic process of Petrochemical industry, including catalytic isomerization, reduction, and cracking are reviewed in this paper. The mechanisms of coke deposition over solid acid catalysts and bi-functional noble metal acid catalysts are summarized. The causes of coke formation under different temperatures are also discussed. Bases on the preliminary results of catalytic cracking of n-heptane over zeolites in our work, identification and assignment of IR absorption bands for coked substances as the key issues on application of in sute FTIR are put forword. Extended applications to the mechanisms of other catalytic reactions and the properties of catalysts are proposed.

Key words: in situ FTIR, coking, catalytic cracking, catalysts

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