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Progress in Chemistry 2008, Vol. 20 Issue (0708): 1208-1215 Previous Articles   Next Articles

• Review •

Ceramic Modification of the Porous Stainless-Steel Surface Toward the Supported Palladium Membranes for Hydrogen Separation

Yu Jian; Hu Xiaojuan; Huang Yan**

  

  1. (State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemistry and Chemical Engineering, Nanjing University of Technology , Nanjing 210009, China)
  • Received: Revised: Online: Published:
  • Contact: Huang Yan
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The composite palladium membrane comprises a porous substrate and a thin layer of palladium or Pd-alloy which is highly permeable for hydrogen. These membranes can be applied in production and recovery of hydrogen, and they can be also employed as membrane reactors which couple the reaction with separation together. In recent years, a great progress has been achieved in development of the palladium membranes based on porous stainless-steel substrates, which helps to ease the problems of membrane sealing and assembling, and therefore makes the membranes more feasible in industry. Since the porous stainless-steel in general is unsuitable to be employed directly as membrane substrate, its surface should be modified with a ceramic layer. This review introduces the stainless-steel material, surface ceramic coating and the membrane layer, wherein the ceramic modification of the stainless-steel surface, as a key process in membrane development, is particularly elucidated in detail.
Key words: porous stainless-steel, composite palladium membrane, ceramic coating, surface modification, hydrogen separation

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