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Progress in Chemistry 2008, Vol. 20 Issue (0708): 1180-1186 Previous Articles   Next Articles

• Review •

Photochemical Degradation of Polybrominated Diphenyl Ethers

Fang Lei; Huang Jun; Yu Gang**

  

  1. (Department of Environmental Science and Engineering, Tsinghua University, Beijing 100084, China)
  • Received: Revised: Online: Published:
  • Contact: Yu Gang
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Polybrominated diphenyl ethers (PBDEs) are considered as a group of global organic pollutants, and have recently received increasing concerns due to their persistence, toxicity and potential for bioaccumulation. Photochemical degradation is one of the important fates for PBDEs in natural environment. In this paper, recent developments about the photochemical degradation of PBDEs under artificial UV light or sunlight in different matrices are reviewed, such as organic solvents, water and solid. Not only the influences of light sources, reaction matrices, number of bromine substituents and substitution pattern on the photolysis rates and photoproducts of PBDEs are introduced, but also the quantitative structure-property relationships based on the photochemical degradation of PBDEs are referred. In addition, the research prospects about the photochemical behavior of PBDEs in the environment are proposed.
Key words: polybrominated diphenyl ethers (PBDEs), photolysis, reductive debromination, quantitative structure-property relationship (QSPR)

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