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Progress in Chemistry 2008, Vol. 20 Issue (0708): 1128-1135 Previous Articles   Next Articles

• Review •

Reversible Addition Fragmentation Chain Transfer Polymerization Mediated by Xanthate

Jiang Bo1 Yi Lingmin1,2** Zhan Xiaoli1** Chen Bi1 Chen Fengqiu1   

  1. (1. Department of Chemical and Biochemical Engineering, Zhejiang University, Hangzhou, 310027, China; 2. Key Laboratory of Advanced Textile Materials and Manufacturing Technology of Ministry of Education, Zhejiang Sci-Tech University, Hangzhou 310018, China)
  • Received: Revised: Online: Published:
  • Contact: Zhan Xiaoli
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The RAFT radical polymerization of non-conjugated vinyl monomers and conjugated vinyl monomers mediated by xanthate are reviewed in this paper. Because the alkyloxy in xanthate (Z group) increases the electron density on central carbon atom of xanthate and stabilizes the fragmentation product, the RAFT radical polymerization of non-conjugated vinyl monomers mediated by xanthate could proceed in a living way. Introducing fluorin atom into Z group of xanthate improves fragmentation of intermedia by decreasing the stabilization of intermedia, instead of stabilizing the fragmentation product. Mediated by this kind of xanthate, conjugated vinyl monomers could be polymerized in a living radical way. Moreover, block copolymers comprised of non-conjugated vinyl monomer and conjugated vinyl monomer can be prepared by fluorinated xanthate.
Key words: xanthate, reversible addition fragmentation chain transfer(RAFT), vinyl acetate, styrene

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