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Progress in Chemistry 2008, Vol. 20 Issue (0708): 1122-1127 Previous Articles   Next Articles

• Review •

Surface-Initiated Living Radical Polymerization from Inorganic Nanomaterials

Sui Xiaofeng Yuan Jinying** Yuan Weizhong Zhou Mi   

  1. （Key Laboratory of Organic Optoelectronics and Molecular Engineering of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084, China）
  • Received: Revised: Online: Published:
  • Contact: Yuan Jinying
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The inorganic-polymer hybrid nanomaterials have many excellent properties. So they are becoming increasingly important for various applications ranging from biomaterials to semiconductors in many fields and arouse much interest of scientists all over the world. This review highlights the development of surface-initiated living radical polymerizations from the inorganic materials including surface-initiated atom transfer radical polymerization(ATRP), surface-initiated addition-fragmentation chain transfer radical polymerization(RAFT), surface-initiated nitroxide-medicated polymerization(NMP) in thr preparation of inorganic-polymer hybrid nanomaterials. The emphasis is put upon the new developments of various approaches taken to prepare hybrid nanomaterials in the recent years. Also, new research trends are pointed out.

Key words: inorganic nanomaterials, surface initiated polymerization, initiation systems

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