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Progress in Chemistry 2008, Vol. 20 Issue (0708): 1108-1114 Previous Articles   Next Articles

• Review •

Asymmetric Transformation of Carbonyl Compounds Using Plant Cells

Liu Xiang1,2** Zhang Baoli1 Xia Yongmei1 Fang Zhijie2 Xu Jianhe3   

  1. (1. School of Chemical and Material Engineering, Jiangnan University, Wuxi 214122, China; 2. School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China; 3. State Key Laboratory of Bioreactor Engineering, East China University of Science and Technology, Shanghai 200237, China)
  • Received: Revised: Online: Published:
  • Contact: Liu Xiang
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Recent progress in asymmetric transformation of carbonyl compounds using plant cells is reviewed in this paper. Using plant cells, not only carbonyl group of some ketones and α- keto esters or β-keto esters can be enantioselectively reduced, but also asymmetric hydroxycyanidation of carbonyl group of some aldehydes can be catalyzed. Furthermore, C＝C double bonds of some unsaturated carbonyl compounds can also be regioselectively transformed. Asymmetric transformation of substrate is influenced by regioselectivity and stereoselectivity of cells from different plant even different part of the same plant. The results of asymmetric transformation can also be affected by steric effect and electronic effect of substitute group of the substrate. Influence of steric effect on asymmetric transformation is more prominent.
Key words: plant cells, carbonyl compounds, biocatalysis, asymmetric transformation

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