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Progress in Chemistry 2008, Vol. 20 Issue (0708): 1073-1089 Previous Articles   Next Articles

• Review •

Rare Earth Complexes with Nitroxide Radicals

Yang Xuhong; Yang Shutao; Wang Shuping**

  

  1. (College of Chemistry & Material Science, Hebei Normal University, Shijiazhuang 050016, China)
  • Received: Revised: Online: Published:
  • Contact: shuping wang
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Rare earth complexes with nitroxide radicals show novel optical and magnetic properties. It is one of the hotspots for molecule-based magnets and multi-functional molecular materials. The structural characteristics, magnetic and optical properties for this kind of complexes are reviewed in this paper, and the influencing factors are also discussed.
Key words: rare earth, nitroxide radical, complex, magnetic property, optical property

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[ 1 ] Miller J S , Drilon M, Eds. Magnetism: Molecules to Materials ( Ⅰ—Ⅳ) . Weinheim: Willey-VCH. 2002
[ 2 ] Caneschi A , Gatteschi D , Sessoli R , et al . Acc. Chem. Res. ,1989 , 22 : 392 —398
[ 3 ] Caneschi A , Gatteschi D , Rey P. Prog. Inorg. Chem. , 1991 ,39 : 331 —429
[ 4 ] Caneschi A , Gatteschi D , Laugier J , et al . J . Am. Chem. Soc. ,1987 , 109 : 2191 —2192
[ 5 ] Caneschi A , Gatteschi D , Rey P , et al . Inorg. Chem. , 1988 ,27 : 1756 —1761
[ 6 ] Caneschi A , Gatteschi D , Renard J P , et al . Inorg. Chem. ,1989 , 28 : 3314 —3319
[ 7 ] Caneschi A , Gatteschi D , Renard J P , et al . Inorg. Chem. ,1989 , 28 : 2940 —2944
[ 8 ] Leuenberger M N , Loss D. Nature , 2001 , 410 : 789 —793
[ 9 ] Glauber R J . J . Math. Phys. , 1963 , 4 : 294 —307
[10] Caneschi A , Gatteschi D , Lalioti N , et al . Angew. Chem. Int .Ed. , 2001 , 40 : 1760 —1763
[11] Benelli C , Caneschi A , Gatteschi D , et al . Inorg. Chem. , 1990 ,29 : 4223 —4228
[12] Benelli C , Caneschi A , Gatteschi D , et al . Inorg. Chem. , 1989 ,28 : 275 —280
[13] Benelli C , Caneschi A , Fabretti A , et al . Inorg. Chem. , 1990 ,29 : 4153 —4155
[14] Benelli C , Caneschi A , Gatteschi D , et al . Angew. Chem. Int .Ed. , 1987 , 26 : 913 —915
[15] Zhao Q H , Ma YP , Du L , et al . Transition Met . Chem. , 2006 ,31 : 593 —597
[16] 姜宗慧(Jiang Z H) , 张伟(Zhang W) , 廖代正(Liao D Z) 等.高等学校化学学报(Chem. J . Chin. Univ. ) , 1996 , 17 (5) :680 —683
[17] Benelli C , Caneschi A , Gatteschi D , et al . Inorg. Chem. , 1992 ,31 : 741 —746
[18] Lescop C , Luneau D , Rey P , et al . Inorg. Chem. , 2002 , 41 :5566 —5574
[19] Tsukuda T , Suzuki T , Kaizaki S. J . Chem. Soc. Dalton Trans. ,2002 : 1721 —1726
[20] Tsukuda T , Suzuki T , Kaizaki S. Inorg. Chim. Acta , 2005 ,358 : 1253 —1257
[21] Sutter J P , Kahn M L , Golhen S , et al . Chem. Eur. J . , 1998 ,4 : 571 —576
[22] Kahn M L , Sutter J P , Golhen S , et al . J . Am. Chem. Soc. ,2000 , 122 : 3413 —3421
[23] Lescop C , Luneau D , Bussière G, et al . Inorg. Chem. , 2000 ,39 : 3740 —3741
[24] Li D J , Gao D Z , Li L C , et al . Chinese J . Struct . Chem. , 24 :905 —908
[25] Li D J , Gao D Z , Liao D Z , et al . J . Coord. Chem. , 2004 , 57 :1571 —1576
[26] Li D J , Wang S P , Liao D Z , et al . J . Mol . Struct . , 2004 ,698 : 103 —107
[27] Lescop C , Belorizky E , Luneau D , et al . Inorg. Chem. , 2002 ,41 : 3375 —3384
[28] Lescop C , Luneau D , Belorizky E , et al . Inorg. Chem. , 1999 ,38 : 5472 —5473
[29] Benelli C , Caneschi A , Gatteschi D , et al . Inorg. Chem. , 1989 ,28 : 272 —275
[30] Benelli C , Gatteschi D. Chem. Rev. , 2002 , 102 : 2369 —2387
[31] Tsukuda T , Suzuki T , Kaizaki S. Mol . Cryst . Liq. Cryst . ,2002 , 379 : 159 —164
[32] Hsu C F , Lin S H , Wei H H. Inorg. Chem. Commun. , 2005 ,8 : 1128 —1132
[33] Luneau D , Rey P. Coord. Chem. Rev. , 2005 , 249 : 2591 —2611
[34] Benelli C , Caneschi A , Gatteschi D , et al . Inorg. Chem. , 1993 ,32 : 4797 —4800
[35] Bogani L , Sangregorio C , Sessoli R , et al . Angew. Chem. Int .Ed. , 2005 , 44 : 5817 —5821
[36] Bernot K, Bogani L , Caneschi A , et al . J . Am. Chem. Soc. ,2006 , 128 : 7947 —7956
[37] Bernot K, Bogani L , Sessoli R , et al . Inorg. Chim. Acta , 2007 ,360 : 3807 —3812
[38] Kaizaki S , Shirotani D , Tsukahara Y, et al . Eur. J . Inorg.Chem. , 2005 : 3503 —3505
[39] Kaizaki S. Coord. Chem. Rev. , 2006 , 250 : 1804 —1818
[40] Bussire G, Beaulac R , Blisle H , et al . Top. Curr. Chem. ,2004 , 241 : 97 —118
[41] Lescop C , Bussiere G, Beaulac Remi , et al . J . Phys. Chem.Solids , 2004 , 65 : 773 —779
[42] Tsukuda T , Ogita M, Suzuki T , et al . Eur. J . Inorg. Chem. ,2004 , 4463 —4469
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