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Progress in Chemistry 2008, Vol. 20 Issue (0708): 1021-1031 Previous Articles   Next Articles

• Review •

Heterogeneous Catalysts for Olefin Cross-Metathesis

Li Xin; Zhang Weiping**; Li Xiujie; Liu Shenglin   

  1. (State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China)
  • Received: Revised: Online: Published:
  • Contact: Zhang Weiping
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Olefin metathesis has been widely used in the fields of petrochemical industry and organic synthesis. It can be classified as ring-opening metathesis, ring-opening metathesis polymerization, ring-closing metathesis, cross-metathesis, etc. Recent developments in the heterogeneous catalysts for olefin cross-metathesis are summarized in this review. Much attention has been paid not only to the heterogeneous catalysts based on Re, Mo and W, but also to the effects that may influence the catalyst activity, such as the metal oxidation state, structure and dispersion of the active species, properties of the support and the addition of promoters, etc. The reaction mechanisms and possible deactivation routes are also discussed in detail.
Key words: olefin cross-metathesis, heterogeneous catalysts, reaction mechanisms, deactivation

CLC Number: 

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