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Progress in Chemistry 2008, Vol. 20 Issue (0708): 1001-1014   Next Articles

• Invited Article •

Polymer Controlled Biomimetic Mineralization

Cai Guobin; Guo Xiaohui; Yu Shuhong**   

  1. (Division of Nanomaterials & Chemistry, Hefei National Laboratory for Physical Sciences at the Microscale, Department of Chemistry, University of Science and Technology of China, Hefei 230026, China)
  • Received: Revised: Online: Published:
  • Contact: Yu Shuhong
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Recently, bio-inspired synthetic strategies for functional materials have gained lots of attentions due to their advantages. This review focuses on recent progresses in biomimetic mineralizations using molecular templates, morphology and structure control for inorganic and inorganic-organic hybrid materials using molecular templates, and the synergetic effects of molecular and solid matrix. We focus on template effects of simple organic additives such as hydrophilic polymer, polyelectrolyte, and surfactant, and their synergestic effects in growth of complex inorganic superstructures and new effects in a mixed solvent. The mechanisms used in biomimetic mineralization for control of new inorganic nanomaterials and inorganic-organic hybrid materials will be discussed. Recent progress indicates that it is possible to control morphologies of all inorganic crystals and hybrid structures via choosing a proper molecular template, a solid matrix, suitable reaction micro-environments, and appropriate self-assembly mechanisms. These materials with controllable length scale and complex form may have potential applications in various fields.
Key words: calcium carbonates, polymers, bio-inspired, biomineralization, biomimetic mineralization

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