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Progress in Chemistry 2008, Vol. 20 Issue (06): 909-917 Previous Articles   Next Articles

• Review •

Exohedral Functionalization of Endohedral Metallofullerenes

Lian Yongfu1** Yuan Fulong1 Guo Lihua2 Liu Meiling1   

  1. 1.College of chemistry chemical engnerring and Materials, Heilongjiang University, Harbin 150083, China; 2.Faculty of Physics and Chemistry, Harbin Normal University, Harbin 150080, China)
  • Received: Revised: Online: Published:
  • Contact: Lian Yongfu
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Owning to their unique structures and novel properties, Endohedral metallofullerenes, i.e. fullerenes with metallic species inside the hollow cage, have attracted much attention of chemists, physicists and even biologists. With the rapid improvement of metallofullerenes chemistry, exohedral functionalization is proven to be essential to determine the structure and property of metallofullerenes and to broaden their applications in various fields. Based on the classification of interaction and chemical reaction by nature, the development of exohedral functionalization of metallofullerenes in recent years is comprehensively reviewed, including cycloaddion reaction, self-assembly with crown ethers, singly bonded derivatives, water-soluble derivatives and filling of single-walled carbon nanotubes, etc. The potential applications of functionalized metallofullerenes are also remarked, and the future prospects for exohedral functionalization of metallofullerenes are presented.
Key words: fullerenes, endohedral metallofullerenes, carbon nanotubes, chemical functionalization, cycloaddition

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