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Progress in Chemistry 2008, Vol. 20 Issue (06): 821-827 Previous Articles   Next Articles

• Review •

Theoretical Studies of Nonideal Electrochemical Behavior of Self-assembled System

Guo Yan; Zhao Jianwei**

  

  1. (Key laboratory of Analytical Chemistry for Life Sciences, Ministry of Education, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210008, China)
  • Received: Revised: Online: Published:
  • Contact: Zhao Jianwei
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Electrochemistry studies of self-assembled systems show the intermolecular interaction among the redox species can significantly influence the electrochemical behavior, exhibiting such as peak broadening or double peaks phenomena. Knowing these non-ideal electrochemical behaviors is very indispensible for the theoretical analysis of the thermodynamic and kinetic information of the system. Focusing on these issues, we summarize the theoretical models and formulism behind the experimental observation in this review. Understanding the underlying mechanism of how the intermolecular interaction affects the electrochemical non-idealities is not only instructive for surface electrochemistry, but also important for those research hotspots such as Host-guest recognition, molecular electron devices, and biosensors.
Key words: intermolecular interaction, electrochemistry, self-assembled monolayer, theoretical models, reorganization energy

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