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Progress in Chemistry 2008, Vol. 20 Issue (05): 698-712 Previous Articles   Next Articles

• Review •

Synthesis of Chiral Ionic Liquids

Sun Honghai1,2 Gao Yu3 Zhai Yongai1 Zhang Qing1 Liu Fengqi1 Gao Ge1*   

  1. (1. College of Chemistry, Jilin University, Changchun 130023, China; 2. Department of Chemistry, Daqing Nornal University, Daqing 163712, China; 3. Health Science Center, Peking University, Beijing 100083, China)
  • Received: Revised: Online: Published:
  • Contact: Gao Ge
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The interest in using room temperature ionic liquids(RTILs) as potential replacement solvents for organic synthesis, extraction, electrochemistry, and materials science had increased tremendously in the recent years. Among them, chiral ionic liquids are particularly attractive due to their potential for chiral discrimination, asymmetric synthesis, optical resolution of racemates, stereoselective polymerization, gas chromatography, NMR shift reagents and liquid crystals. Even though the difficult synthesis of chiral ionic liquids and their high cost often precluded their use, the possibility to use chiral ionic liquids as inducers for asymmetric reactions has greatly prompted researchers to continuely synthesize new chiral solvents. The chiral ionic liquids are designed either from the chiral pool (aminoacids, amines, aminoalcohols, and alkaloids) or by asymmetric synthesis; they can bear center, axial or planar chirality. This review deals mainly with recent advances in synthesis of chiral ionic liquids. Based on the species of cation or anion, they are classified into imidazolium-based, pyridinium-based, ammonium-based, and thiazolinium-based etc. In addition, some new synthesis techniques are also introduced.

Key words: chirality, ionic liquid, synthesis

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Abstract

Synthesis of Chiral Ionic Liquids