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Progress in Chemistry 2008, Vol. 20 Issue (05): 673-678 Previous Articles   Next Articles

• Review •

Organic Compounds with Aggregation-Induced Emission

Qian Lijun1 Zhi Junge2 Tong Bin1 Yang Fan1 Zhao Wei1 Dong Yuping1**   

  1. (1. College of Materials Science & Engineering, Beijing Institute of Technology, Beijing 100081, China; 2. College of Science, Beijing Institute of Technology, Beijing 100081, China)
  • Received: Revised: Online: Published:
  • Contact: Dong Yuping
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Light emissions of the organic dyes are, however, often quenched when the luminophors are fabricated into solid thin films, which have greatly limited their scope of practical applications, such as organic light-emitting diodes, chemosensors/biosensors etc. So that, the organic compounds with excellent emission properties at aggregate state or solid state, that are, aggregation-induced emission (AIE), aggregation-induced emission enhancement(AIEE) and crystallization-induced emission enhancement(CIEE) properties, attract more and more attention. They can get tunable intensity and wavelength of emission by adjusting molecular structure, twisted conformation, rigidity of structure and stack morphology etc. The review focuses on the structures and mechanisms about AIE, AIEE and CIEE. The kinds of compounds with AIE, AIEE and CIEE are summarized, mainly including siloles, substituted ethenes (mainly including fulvene and DPDSB style), CN-MBE, pyran, biphenyl compounds and polymers. Herein some theories explaining AIE, AIEE and CIEE are introduced including RIR (Restriction of Intramolecular Rotation), non-activation by avoiding nonradiative decay, preventability of excimers by twisted conformation, J-aggregate state and intermolecular C-H/π interaction .
Key words: aggregation-induced emission, aggregation-induced emission enhancement, crystallizatin-induced emission enhancement

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