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Progress in Chemistry 2008, Vol. 20 Issue (05): 629-636 Previous Articles   Next Articles

• Review •

New Methods for Tuning Band Gap of Colloidal Semiconductor Nanocrystals

Gu Zhenyu; Zhu Weihong; Zhong Xinhua**   

  1. (Laboratory for Advanced Materials, School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai 200237, China)
  • Received: Revised: Online: Published:
  • Contact: Zhong Xinhua
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Due to quantum confinement effect, band gap of semiconductor nanocrystals (NCs) is dependent on the particle size. However, tuning band gap of NCs simply by changing particle size may cause problems technically. Herein, we review new concepts and new routes to tune band gap of NCs including alloyed NCs, inverted Type- I and Type- II core/shell structur and their corresponding advantages.
Key words: colloid, semiconductor nanocrystals, band gap engineering, alloyed nanocrystals, core/shell structure

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[ 1 ] Rossetti R , Nakahara S , Brus L E. J . Chem. Phys. , 1983 , 79 :1086 —1109
[ 2 ] Weller H. Angew. Chem. , 1993 , 105 : 43 —55
[ 3 ] Heath J R. Acc. Chem. Res. , 1999 , 32 : 389 —414
[ 4 ] Colvin V L , Schlamp M C , Alivisatos A P. Nature , 1994 , 370 :354 —357
[ 5 ] Tessler N , Medvedev V , Kazes M, Kan S H , Banin U. Science ,2002 , 295 : 1506 —1508
[ 6 ] Klimov V I , Mikhailovsky A A , Xu S , Malko A , Hollingsworth J A , Leatherdale C A , Eisler H J , Bawendi M G. Science , 2000 ,290 : 314 —317
[ 7 ] Kazes M, Lewis D Y, Ebenstein Y, Mokari T , Banin U. Adv.Mater. , 2002 , 14 : 317 —321
[ 8 ] Warren C W, Nie S M. Science , 1998 , 281 : 2016 —2018
[ 9 ] Bruchez M, Moronne M, Gin P , Weiss S , Alivisatos A P.Science , 1998 , 281 : 2013 —2016
[10] Yoffe A D. Adv. Physics , 2001 , 50 : 1 —208
[11] Steigerwald M L , Brus L E. Acc. Chem. Res. , 1990 , 23 :183 —188
[12] Trindade T , O’Brien P , Pickett P L. Chem. Mater. , 2001 , 13 :3843 —3858
[13] Donegá C M, Liljeroth P , Vanmaekelbergh D. Small , 2005 , 1 :1152 —1162
[14] Chen A B , Sher A. Semiconductor Alloys. New York : Plenum Press , 1996
[15] Hetterich M, Petillon S , Petri W, Dinger A , Grun M, Klingshrin C. J . Cryst . Growth , 1996 , 159 : 81 —84
[16] Colli A , Hofmann S , Ferrari A C , Martelli F , Rubini S , Ducati C , Franciosi A , Robertson J . Nanotechnology , 2005 , 16 : 139 —142
[17] Pan A L , Yang H , Liu R , Yu R C , Zou B S , Wang Z L. J .Am. Chem. Soc. , 2005 , 127 : 15692 —15693
[18] Korgel B A , Monbouquette H G. Langmuir , 2000 , 16 : 3588 —3594
[19] Harrison M T , Kershaw S V , Burt M G, Eychmüller A , Weller H , Rogach A L. Mater. Sci . Eng. B , 2000 , 69 : 355 —360
[20] Kershaw S V , Burt M G, Harrison M T , Rogach A L , Weller H ,Eychmüller A. Appl . Phys. Lett . , 1999 , 75 : 1694 —1696
[21] Rogach A L , Harrison M T , Kershaw S V , Kornowski A , Burt M G, Eychmüller A , Weller H. Phys. Stat . Sol . B , 2001 , 224 :153 —158
[22] Petrov D V , Santos B S , Pereira G A L , DonegáC D M. J .Phys. Chem. B , 2002 , 106 : 5325 —5334
[23] Wang W, Germanenko I , El-Shall M S. Chem. Mater. , 2002 ,14 : 3028 —3033
[24] Zhong X H , Han M Y, Dong Z L , White T J , Knoll W. J . Am.Chem. Soc. , 2003 , 125 : 8589 —8594
[25] Sung Y M, Lee Y J , Park K S. J . Am. Chem. Soc. , 2006 ,128 : 9002 —9003
[26] Zhong X H , Feng Y Y, Knoll W, Han M Y. J . Am. Chem.Soc. , 2003 , 125 : 13559 —13563
[27] Zhong X H , Zhang Z , Liu S , Knoll W, Han M Y. J . Phys.Chem. B , 2004 , 108 : 15552 —15559
[28] Zhong X H , Liu S , Zhang Z , Li L , Wei Z , Knoll W. J . Mater.Chem. , 2004 , 14 : 2790 —2794
[29] Nie Q L , Yuan Q L , Wang Q S , Xu Z D. J . Mater. Sci . , 2004 ,39 : 5611 —5612
[30] Ge J , Xu S , Zhuang J , Wang X, Peng Q , Li Y. Inorg. Chem. ,2006 , 45 : 4922 —4927
[31] Li Y, Ye M, Yang C , Li X, Li Y. Adv. Funct . Mater. , 2005 ,15 : 433 —441
[32] DeGroot M W, Corrigan J F. Angew. Chem. Int . Ed. , 2004 ,43 : 5355 —5357
[33] DeGroot M W, Taylor N J , Corrigan J F. Inorg. Chem. , 2005 ,44 : 5447 —5458
[34] DeGroot M W, Taylor N J , Corrigan J F. J . Am. Chem. Soc. ,2003 , 125 : 864 —865
[35] DeGroot M W, Taylor N J , Corrigan J F. J . Mater. Chem. ,2004 , 14 : 654 —660
[36] DeGroot M W, Corrigan J F. Chem. Eur. J . , 2006 , 12 : 1547 —1554
[37] Shaw D. J . Cryst . Growth , 1988 , 86 : 778 —796
[38] Bailey R E , Nie S M. J . Am. Chem. Soc. , 2003 , 125 : 7100 —7106
[39] Poon H C , Feng Z C , Feng Y P , Li M F. J . Phys. Condens.Matter , 1995 , 7 : 2783 —2799
[40] Jiang W, Anupam S , Zheng J N , Wang C , Chan WC W. Chem.Mater. , 2006 , 18 : 4845 —4854
[41] Thomas F , Josef M, Thomas A K, Andrey L R , Jochen F , Dmitri V T , Weller H. J . Phys. Chem. C , 2007 , 111 : 2974 —2979
[42] Swafford L A , Weigand L A , Bowers M J , McBride J R , Rapaport J L , Watt TL , Dixit S K, Feldman L C , Rosenthal S J . J . Am.Chem. Soc. , 2006 , 128 : 12299 —12306
[43] Spanhel L , Haase M, Weller H , Henglein A. J . Am. Chem.Soc. , 1987 , 109 : 5649 —5655
[44] Murray C B , Norris D J , Bawendi M G. J . Am. Chem. Soc. ,1993 , 115 : 8706 —8715
[45] Yu W W, Peng X G. Angew. Chem. Int . Ed. , 2002 , 41 :2368 —2371
[46] Kortan A R , Hull R , Opila R L , Bawendi M G, Steigerwald M L , Carrol P J , Brus L E. J . Am. Chem. Soc. , 1990 , 112 :1327 —1332
[47] Dabbousi B , Rodriguez-Viejo J , Mikulec F , Heine J , Mattoussi H , Ober R , Jensen K, Bawendi M G. J . Phys. Chem. B , 1997 ,101 : 9463 —9475
[48] Danek M, Jensen K F , Murray C B , Bawendi M G. Chem.Mater. , 1996 , 8 : 173 —180
[49] Peng X G, Schlamp M C , Kadavanich A V , Alivisatos A P. J .Am. Chem. Soc. , 1997 , 119 : 7019 —7029
[50] Ishizumi A , Kanemitsu Y. Adv. Mater. , 2006 , 18 : 1083 —1085
[51] Bao H , Gong Y, Gao M. Chem. Mater. , 2004 , 16 : 3853 —3859
[52] Gaponik N , Talapin D V , Rogach AL , Eychmüller A , Weller H.Nano Lett . , 2002 , 2 : 803 —806
[53] Li J J , Wang YA , Guo W Z , Keay J C , Mishima T D , Johnson M B , Peng X G. J . Am. Chem. Soc. , 2003 , 125 : 12567 —12575
[54] Xie R G, Kolb U , Li J , BaschéT , Mews A. J . Am. Chem.Soc. , 2005 , 127 : 7480 —7488
[55] Haus J W, Zhou H S , Honma I , Komiyama H. Phys. Rev. B ,1993 , 47 : 1359 —1377
[56] Schooss D , Mews A , Eychmüller A , Weller H. Phys. Rev. B ,1994 , 49 : 17072 —17084
[57] Mews A , Eychmüeller A , Giersig M, Schooss D , Weller H. J .Phys. Chem. , 1994 , 98 : 934 —941
[58] Alivisatos A P. Science , 1996 , 271 : 933 —937
[59] Little R B , El-Sayed M A , Bryant G W, Burke S. J . Chem.Phys. , 2001 , 114 : 1813 —1822
[60] Chang K, Xia J B. Phys. Rev. B , 1998 , 57 : 9780 —9793
[61] Dorfs D , Henschel H , Kolny J , Eychmüller A. J . Phys. Chem.B , 2004 , 108 : 1578 —1583
[62] Battaglia D , Li J J , Wang Y, Peng X G. Angew. Chem. Int .Ed. , 2003 , 42 : 5035 —5039
[63] Zhong X H , Xie R G, Zhang Y, Basché T , Knoll W. Chem.Mater. , 2005 , 17 : 4038 —4042
[64] Mikhailovsky A A , Malko A V , Hollingsworth J A , Bawendi M G, Klimov V I. Appl . Phys. Lett . , 2002 , 80 : 2380 —2382
[65] Kazes M, Lewis D Y, Ebenstein Y, Mokari T , Banin U. Adv.Mater. , 2002 , 14 : 317 —321
[66] Balet L P , Ivanov S A , Piryatinski A , Achermann M, Klimov V I. Nano Lett . , 2004 , 4 : 1485 —1488
[67] Ivanov S A , Nanda J , Piryatinski A , Achermann M, Balet L P ,Bezel I V , Anikeeva P O , Tretiak S , Klimov V I. J . Phys.Chem. B , 2004 , 108 : 10625 —10630
[68] Laheld U E H , Pedersen F B , Hemmer P C. Phys. Rev. B ,1995 , 52 : 2697 —2711
[69] Hatami F , Grundmann M, Ledentsov N N , Heinrichsdorff F ,Heitz R , Bêhrer J , Bimberg D , Ruvimov S S , Werner P , Ustinov V M, Kop ’ev P S , Alferov Z I. Phys. Rev. B , 1998 , 57 :4635 —4672
[70] Youn H C , Baral S , Fendler J H. J . Phys. Chem. , 1998 , 92 :6320 —6327
[71] Kim S , Fisher B , Eisler H J , Bawendi M G. J . Am. Chem.Soc. , 2003 , 125 : 11466 —11467
[72] Kim S , Lim Y T , Soltesz E G, De Grand A M, Lee J , Nakayama A , Parker J A , Mihaljevic T , Laurence R G, Dor D M, Cohn L H , Bawendi M G, Frangioni J V. Nat . Biotechnol . , 2004 , 22 :93 —97
[73] Yu K, Zaman B , Romanova S , Wang D , Ripmeester J A. Small ,2005 , 1 : 332 —338
[74] Li J J , Tsay J M, Michalet X, Weiss S. Chem. Phys. , 2005 ,318 : 82 —90
[75] Xie R G, Zhong X H , BaschéT. Adv. Mater. , 2005 , 17 :2745 —2748
[76] Chen C Y, Cheng C T , Yu J K, Pu S C , Cheng Y M, Chou P T ,Chou Y H , Chiu H T. J . Phys. Chem. B , 2004 , 108 : 10687 —10691
[77] Wang C H , Chen T T , Tan K W, Chen Y F , Cheng C T , Chou P T. J . Appl . Phys. , 2006 , 99 : 123521 —123524
[78] Chou P T , Chen C Y, Cheng C T , Pu S C , Wu K C , Cheng Y M, Lai C W, Chou Y H , Chiu H T. ChemPhysChem, 2006 , 7 :222 —228
[79] Cheng C T , Chen C Y, Lai C W, Liu W H , Pu S C , Chou P T ,Chou YH , Chiu H T. J . Mater. Chem. , 2005 , 15 : 3409 —3414
[80] Chen C Y, Cheng C T , Lai C W, Hu Y H , Chou P T , Chou Y H , Chiu H T. Small , 2005 , 1 : 1215 —1220
[81] Milliron D J , Hughes S M, Cui Y, Manna L , Li J , Wang L W,Alivisatos A P. Nature , 2004 , 430 : 190 —195
[82] Peng P , Milliron D J , Hughes S M, Johnson J C , Alivisatos A P ,Saykally R J . Nano Lett . , 2005 , 9 : 1809 —1813
[83] Halpert J E , Porter V J , Zimmer J P , Bawendi M G. J . Am.Chem. Soc. , 2006 , 128 : 12590 —12591
[84] Xie R G, Kolb U , Basché T. Small , 2006 , 2 : 1454 —1457
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