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Progress in Chemistry 2008, Vol. 20 Issue (04): 469-482 Previous Articles   Next Articles

• Review •

Liquid Phase Oxidation Reactions Catalyzed by Polyoxometalates

Lang Xianjun1,2 Lu Ruiling1,2 Li Zhen1 Xia Chungu1**   

  1. (1. State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China; 2. Graduate School of Chinese Academy of Sciences, Beijing 100049, China)
  • Received: Revised: Online: Published:
  • Contact: Xia Chungu
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After a brief introduction to the structure and general properties of polyoxometalates, the unusual versatility and tunability and their compatibility with environmentally and economically attractive conditions (solvents, oxidants, etc.) are outlined. These characteristics enable polyoxometalates suitable for catalyst to design at the atomic/molecular levels and applicable in the aspects of green catalysis and clean production. Recent developments of clean oxidation systems catalyzed by polyoxometalates are summarized in detail. The emphasis is on the epoxidation reaction of olefinic compounds, oxidation of alkanes and aromatic compounds with the comparatively ideal oxidants, hydrogen peroxide and molecular oxygen respectively. The oxidation mechanisms are elucidated in detail. In addition, the applications of polyoxometalate in the area of biomimetic catalysis are discussed.
Key words: polyoxometalate, clean oxidation, hydrogen peroxide, molecular oxygen, biomimetic catalysis

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