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Progress in Chemistry 2008, Vol. 20 Issue (04): 464-468 Previous Articles   Next Articles

• Review •

Polymer-Laponite Nanocomposite Hydrogels with Super-Elongation

Xiong Lijun; Hu Xiaobo; Liu Xinxing; Tong Zhen**   

  1. (Research Institute of Materials Science, South China University of Technology,
    Guangzhou 510640, China)
  • Received: Revised: Online: Published:
  • Contact: Tong Zhen
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A novel nanocomposite hydrogel was prepared by in-situ radical polymerization of acrylamide monomers in the suspension of Laponite clay without cross-linkers. Laponite particle is a lamellar disk with diameter of 25-30 nm and thickness of 1 nm, which is believed to take the role of cross-linker in the hydrogel. This kind of hydrogel becomes the focus of smart materials with high transparency and excellent mechanical properties, which can be elongated up to 1 300%. Up to now, only acrylamide derivatives can be used in this polymerization. In this paper, we reviewed the recent research on the monomer, Laponite used in the gel and synthesis, structure, physical properties of the nanocomposite hydrogels with the structure and properties of Laponite. The possible development of this nanocomposite hydrogel in the near future is also discussed.
Key words: Laponite, hydrogel, smart materials, macromolecular network

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[ 1 ] Shibayama M, Tanaka T. Adv. Polym. Sci . , 1993 , 109 : 3 —62
[ 2 ] Haraguchi K, Takehisa T. Adv. Mater. , 2002 , 14 : 1120 —1124
[ 3 ] Haraguchi K, Takehisa T , Fan S. Macromolecules , 2002 , 35 :10162 —10171
[ 4 ] Haraguchi K, Takada T. Macromol . Chem. Phys. , 2005 , 206 :1530 —1540
[ 5 ] Herrera N N , Letoffe J M, Putaux J L , et al . Langmuir , 2004 ,20 : 1564 —1571
[ 6 ] FossumJ O. Physica A , 1999 , 270 : 270 —277
[ 7 ] Huang A Y, Berg J C. J . Colloiol Interface Sci . , 2006 , 296 :159 —164
[ 8 ] Liu X, Thomas J K. Langmuir , 1991 , 7 : 2808 —2816
[ 9 ] Mourchid A , Lécolier E , Damme H V , et al . Langmuir ,1998 ,14 : 4718 —4723
[10] Mourchid A , Levitz P. Phys. Rev. E , 1998 , 57 : R4887 —R4890
[11] Martin C , Pignon F , Piau J M, et al . Phys. Rev. E , 2002 , 66 :art . no. 021401
[12] Kroon M, Vos WL , Wegdam G H. Phys. Rev. E , 1998 , 57 :1962 —1970
[13] Gabriel J C P , Sanchez C , Davidson P. J . Phys. Chem. , 1996 ,100 : 11139 —11143
[14] Labanda J , Llorens J . Rheol Acta , 2006 , 45 : 305 —314
[15] Pignon F , Magnin A , Piau J M, et al . Phys. Rev. E , 1997 , 56 :3281 —3289
[16] Strachan D R , Kalur GL , Raghavan S R. Phys. Rev. E , 2006 ,73 , art . no. 041509
[17] Nicolai T , Cocard S. J . Colloid Interface Sci . , 2001 , 244 :51 —57
[18] Mongondry P , Tassin J F , Nicolai T. J . Colloid Interface Sci . ,2005 , 283 : 397 —405
[19] Ruzicka B , Zulian L , Ruocco G. Phys. Rev. Lett . , 2004 , 93 :258301 —258305
[20] Ruzicka B , Zulian L , Ruocco G. J . Phys. Condens. Matter ,2004 , 16 : S4993 —S5002
[21] Tanaka H , Meunier J , Bonn D. Phys. Rev. E , 2004 , 69 : art .no. 031404
[22] Tanaka H , Meunier J , Bonn D. Phys. Rev. E , 2005 , 71 : art .no. 021402
[23] Ruzicka B , Zulian L , Ruocco G. Langmuir , 2006 , 22 : 1106 —1111
[24] Mourchid A , Delville A , Lambard J , et al . Langmuir , 1995 , 11 :1942 —1950
[25] Nicolai T , Cocard S. Langmuir , 2000 , 16 : 8189 —8193
[26] Nicolai T , Cocard S. Eur. Phys. J . E , 2001 , 5 : 221 —227
[27] Li L , Harnau L , Rosenfeldt S , et al . Phys. Rev. E , 2005 , 72 :art . no. 051504
[28] Norrish K. Discuss. Faraday Soc. , 1954 , 18 : 120 —133
[29] Van Olphen H. J . Colloid. Sci . , 1962 , 17 : 660 —667
[30] Willenbacher N. J . Colloid Interface Sci . , 1996 , 182 : 501 —510
[31] Haraguchi K, Taniguchi S , Takehisa T. ChemPhysChem, 2005 ,6 : 238 —241
[32] Haraguchi K, Farnworth R , Ohbayashi A , et al . Macromolecules ,2003 , 36 : 5732 —5741
[33] Zhu M F , Liu Y, Sun B , et al . Macromol . Rapid Commun. ,2006 , 27 : 1023 —1028
[34] Haraguchi K, Li HJ , Matsuda K, et al . Macromolecules , 2005 ,38 : 3482 —3490
[35] Nie J , Du B , Oppermann W. Macromolecules , 2005 , 38 :5729 —5736
[36] Haraguchi K, Li HJ . Macromolecules , 2006 , 39 : 1898 —1905
[37] Liu Y, Zhu M F , Liu XL , et al . Polymer ,2006 , 47 : 1 —5
[38] Shibayama M, Karino T , Miyazaki S , et al . Macromolecules ,2005 , 38 : 10772 —10781
[39] Shibayama M, Suda J , Karino T , et al . Macromolecules , 2004 ,37 : 9606 —9612
[40] Haraguchi K, Li H J . Angew. Chem. Int . Ed. , 2005 , 44 :6500 —6504
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