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Progress in Chemistry 2008, Vol. 20 Issue (04): 457-463 Previous Articles   Next Articles

• Review •

Hydroisomerization of n-Alkane

Liang Jun; Wang Fuping*   

  1. (Harbin Institute of Technology, Harbin 150001, China)
  • Received: Revised: Online: Published:
  • Contact: Wang Fuping
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The mechanisms of n-alkane hydroisomerization on bifunctional catalyst are reviewed including carbonium ion isomerization and cracking, pore and key-lock catalysis, shape selectivity, and bimolecular reaction. The effects of the charateristics such as acid intensity and strength, metal dispersion, the ratio of metal and acid cites, pore dimension and size, crystal particle size on the acitivity, selectivity of the catalyst are systematically discussed. The recent improvement methods of hydroisomerizaion catalyst are described. The methods of developing the activity and selectivity simultaneously are mentioned for respective kinds of catalyst.
Key words: n-alkanes, hydroisomerization, reaction mechenism, hyadrocracking, molecular sieve

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Abstract

Hydroisomerization of n-Alkane