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Progress in Chemistry 2008, Vol. 20 Issue (04): 441-449 Previous Articles   Next Articles

• Review •

CO2/Ionic Liquids Phase Behaviors and Its Applications for Reaction and Separation

Wang Weibin; Yin Jianzhong*   

  1. (School of Chemical Engineering, Dalian University of Technology, Dalian 116012,China)
  • Received: Revised: Online: Published:
  • Contact: Yin Jianzhong
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It is known that supercritical fluids (SCFs), room-temperature ionic liquids (ILs), CO2 expanded liquids (CXLs), water, as well as their mixtures are currently regarded as green solvents. Among them, the mixtures of SCFs and ILs have received considerable research attention due to their favorable thermodynamic properties. This review summarizes the recent progress in this filed, focusing on the factors that influence the phase behavior of SCFs and ILs, such as pressure, temperature, water contents, molar volume of ILs, co-solvents, anions, and cations. In addition, the phase behavior of the multicomponents containing the coupling solvent ILs/SCCO2 and the solute was also analyzed. Finally, the potential applications of ILs/SCCO2 coupling solvent are proposed, including extraction, anti-extraction, membrane separation, reverse micelle, and separation coupling with reaction. In particular, coupling separation with reaction using SCCO2/ILs as the green solvent will be one of the ways of clean production.
Key words: supercritical CO2, ionic liquids, phase behavior, reaction and separation, process coupling

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