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Progress in Chemistry 2008, Vol. 20 Issue (01): 26-32 Previous Articles   Next Articles

• Review •

Ordered Mesoporous Silica/Polyaniline Composites

Zeng Chunmei; Han Shuhua**; Yan Xin ; Yu Xiaojuan; Che Hongwei; Zhao Xiaohong   

  1. （Key Laboratory of Colloid and Interface Science Chemistry, Ministry of Education, Jinan 250100, China）
  • Received: Revised: Online: Published:
  • Contact: Han Shuhua
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The research progress of ordered mesoporous silica/polyaniline composites are reviewed in this article from the day it appeared to now. The synthesis routes, such as the gas-phase method, the liquid-phase method, the one-step synthesis method and the related template-monomer in situ synthesis method etc., are introduced. Polyaniline, which is polymerized in the mesoporous channels by the filling of aniline monomers, is joined with mesoporous silica to synthsize the composites of mesoporous silica and polyaniline. Compared with bulk polyaniline, the structure and morphologies of the composites, and the structure and electrical properties of polyaniline in the mesoporous channels have greatly changed after formation of composites. The single molecular wire of polyaniline, which is templated by the ordered mesoporous silica, has potential application in the next-generation electronic or optoelectronic materials. Moreover, the composites for its unique properties can be used in various fields, involving polymer electrolyte membrane for fuel cell, humidity sensor, electrorheological material, and electrochemical capacitor.
Key words: ordered mesoporous silica, polyaniline, composites

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