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Progress in Chemistry 2007, Vol. 19 Issue (9): 1413-1418 Previous Articles   Next Articles

• Review •

Dimerization reaction of isobutene

Xu Zehui1,2* Fang Dingye2   

  1. 1. Chemical Research Institute, Shanghai Petrochemical Company Limited, Shanghai 200540, China; 2. Department of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, China

  • Received: Revised: Online: Published:
  • Contact: Xu Zehui
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Because Methyl tert-butyl ether (MTBE) is soluble in water and has been occasionally found its way into ground water from leaking storage tanks, MTBE was environmentally limited as gasoline additive and its production and application prospects is negatively affected. Producing isooctane by MTBE decomposition, dimerization of isobutene(IB) and hydrogenation of diisobutene became the main way for the exiting MTBE units abroad to produce other products. The catalyst for IB dimerization, reactive site, reactive mechanism and dynamics research date was reviewed in this paper and try to explain the mechanism of selectivity enhancing by adding Tertiary butyl alcohol during IB dimerization and provide reference for the study of dimerization afterwards.

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[1] Li Li,Yan Zifeng**. Review of Catalytic Dehydrogenation of Isobutene [J]. Progress in Chemistry, 2005, 17(04): 651-659.
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Abstract

Dimerization reaction of isobutene