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Progress in Chemistry 2007, Vol. 19 Issue (9): 1291-1300 Previous Articles   Next Articles

• Review •

Mixed Cationic and Anionic Surfactants Systems

Nan Yanqing**;Hao Lisheng   

  1. College of Chemistry and Chemical Engineering, Hunan Normal University, Changsha, 410081,China
  • Received: Revised: Online: Published:
  • Contact: Nan Yanqing
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Because of the strong static attraction between the oppositely charged head groups,the mixed cationic and anionic surfactant systems possess strong synergistic effect and high surface activity, can form rich microstructures in aqueous solution and exhibit complicated phase behavior. In this paper, we have reviewed recent progresses in the studies about surface (interface) properties, the preparation and stability of vesicles, the formation and properties of wormlike micelles, and the properties and applications on extraction of aqueous two-phase systems. The studies about the theory investigation (such as pseudo-phase separation model, thermodynamic cell model, molecular thermodynamics and molecular simulation etc.), and the usage as templates of nanomaterial synthesis of mixed cationic/anionic surfactant systems have been reviewed also.　For the research of the aqueous two-phase systems, some questions need to be solved are indicated.
Key words: cationic/anionic surfactants, surface activity, vesicle, worm-like micelles, aqueous two-phase systems, extraction, nanomaterials

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