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Progress in Chemistry 2007, Vol. 19 Issue (10): 1562-1567 Previous Articles   Next Articles

• Review •

Synthesis of Fluoropolymers in Supercritical Carbon Dioxide

Li Hong;Xu An hou;Zhang Yongming**   

  1. School of Chemistry and Chemical Technology, Shanghai Jiaotong University, Shanghai 200240，China
  • Received: Revised: Online: Published:
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Supercritical carbon dioxide is an inexpensive, low-toxic, non-flammable，easily recycled，environmentally benign and inert polymerization medium, which can be used as a polymerization solvent instead of conventional organic solvents. Especially, it is a potential alternative of fluorinated and chlorinated solvents for polymerization of fluorine-containing monomers. In the paper, the polymerization of fluoroalkyl acrylate and fluoroolefins in supercritical carbon dioxide are reviewed in detail，including homopolymerization and copolymerization of fluoroalkyl acrylate, synthesis of melt-processable tetrafluoroethylene polymers, ion-exchange resins and polyvinylidene fluoride et.al. The result shows that polymerizations of fluorinated monomer in supercritical carbon dioxide have some advantages over other solvent systems.
Key words: Supercritical carbon dioxide, Fluoropolymers, Fluoroalkyl acrylates, Fluoroolefins

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