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Progress in Chemistry 2007, Vol. 19 Issue (10): 1553-1562 Previous Articles   Next Articles

• Review •

Polyfluorenes and Its Derivatives for Electroluminescent Materials

Tang Chao1;Liu Feng2;Xu Hui3;Huang Wei1**   

  1. 1. Institute of Advanced Materials, Nanjing University of Posts and Telecommunications, Nanjing, 210003,China;

    2. Institute of Advanced Materials, Fudan University, Shanghai, 200433,China;

    3. School of Optoelectronic Engineering, Nanjing University of Posts and Telecommunications, Nanjing, 210003,China

  • Received: Revised: Online: Published:
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As an important class of electroluminescent polymers, polyfluorene and its derivatives have been paid much attention by hundreds of materials chemists because they have advantages of easy modification and high photoluminescence efficiency. As a whole in this review, the chemical modification aims at developing new electroluminescent materials through tuning frontier molecular orbitals, thermal and luminescent stability. So the focus in this review is on the relationships between the structures of polymers and their light emission properties. The synthesis methods of the polymers are firstly concisely introduced. Then the polymers have been divided into two kinds according to the difference of chemical structure. The one kind is the polymers that the main conjugation chains are only comprised of fluorene units, whose chemical modification is based on the active C9 of fluorene moiety. The other is the polymers that the main chains are comprised of fluorene and other functional groups through copolymerization.
Key words: polyfluorenes, derivatives, electroluminescent polymers, light emission

CLC Number: 

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