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Progress in Chemistry 2007, Vol. 19 Issue (10): 1517-1528 Previous Articles   Next Articles

• Review •

Application of Liquid Poly(Ethylene Glycol)s as Green Reaction Media in Organic Reactions

Zhou Haifeng1,2 ;Fan Qinghua2**; He Yanmei 2;Gu Lianquan 1**;Chan Albert S C 3**   

  1. 1. School of Chemistry and Chemical Engineering, and School of Pharmaceutical Science, Sun Yat-Sen University, Guangzhou 510275, China;

    2. Laboratory of Molecular Recognition and Selective Synthesis, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China;

    3. Department of Applied Biology & Chemical Technology, The Hong Kong Polytechnic University, Kowloon, Hong Kong, China

  • Received: Revised: Online: Published:
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Low molecular weight liquid polyethylene glycols (PEG) as a novel green solvent for organic reactions have been attracting great attention. They are thermally stable, nonvolatile, nonflammable, non-toxic, biodegradable, inexpensive and recyclable. Moreover, they can dissolve a great range of organic compounds and organometallic complexes. Thus, liquid PEG as an alternative to organic solvent and as a new means for homogeneous catalyst immobilization has been successfully employed in a number of organic reactions, such as reduction reaction, hydrogenation, oxidation reaction, asymmetric dihydroxylation, Heck reaction, Suzuki cross-coupling reactions, Michael addition reaction, asymmetric Aldol reaction, Baylis-Hillman reaction, lipase-catalyzed reaction, polymerization reaction and so on. This paper reviews the advances in this research field.

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