中文
Earlier issues
Announcement
More
Progress in Chemistry 2007, Vol. 19 Issue (10): 1481-1487 Previous Articles   Next Articles

• Review •

Catalysts for n-Butane Dehydrogenation to 1-Butene

Xu Yuebing ;Lu Jiangyin**;Wang Jide   

  1. Key Laboratory of Oil&Gas Fine Chemicals, Ministry of Education,Xinjiang University, Urumqi 830046, China
  • Received: Revised: Online: Published:
PDF ( 2096 ) Cited
Export

EndNote

Ris

BibTeX

The series of catalysts for dehydrogention of n-butane to 1-butene, including oxidative dehydrogenation with Vanadium-based 、molybdates、metal pyrphosphates catalysts and catalytic dehydrogenation with Pt-based catalysts and ZSM-5 zeolite, are reviewed, the membrane reactor with catalysts is also discussed . The paper reviews the kinetics for butane dehydrogenation and summerizes the reaction mechanism of n-butane oxydehydrogenation and direct dehydrogenation based on Mars-van Krevlen and Eley-Rideal kinetics and discusses the factors of catalysts simply. It also compares the characteristics between several catalysts and prospects them. Finally, The paper points out that the catalyst of ZSM-5 zeolite will likely be the reserch hotspot for n-butane dehydrogenation to 1-butene.
Key words: n-Butane, Dehydrogenation, Catalysts, Kinetics, Reaction Mechanism

CLC Number: 

[ 1 ] 李丽(Li L) , 高金森(Gao J S) , 孟祥海(Meng X H) . 现代化工(Modern Chem. Industry) , 2003 , 23 : 93 —96
[ 2 ] 李明辉(Li M H) . 石油化工( Petrochemical Technology) ,2003 , 32(9) : 808 —814
[ 3 ] 史立新(Shi L X) , 张宝义(Zhang B Y) , 崔连复(Cui L F) .沈阳化工(Shenyang Chem. Ind. ) , 1995 , (2) : 27 —33
[ 4 ] 黄晓南(Huang X N) , 王新一(Wang X Y) . 天津化工(Tianjin Chemical Industry) , 1996 , (3) : 6 —8
[ 5 ] 刘睿(Liu R) , 王新平(Wang X P) , 贾翠英(Jia C Y) . 催化学报(Chin. J . Catal . ) , 2005 , 26(8) : 650 —654
[ 6 ] Vidal-Michel R , Hohn KL. J . Catal . , 2004 , 221 : 127 —136
[ 7 ] Murgia V , Torres E M F , Gottifredi J C , et al . Appl . Catal . A:General , 2006 , 312 : 134 —143
[ 8 ] Wu Z L , Stair P C. J . Catal . , 2006 , 237 : 220 —229
[ 9 ] Garcia E M, Sanchez M D , Tonetto G, et al . J . Colloid and Interface Sci . , 2005 , 292 : 179 —185
[10] Cortés I , Rubio O , Herguido J , et al . Catal . Today , 2004 , 91/92 : 281 —284
[11] VolPe M, Tonetto G, Lasa H. Appl . Catal . A: General , 2004 ,272 : 69 —78
[12] Ge S H , Liu C H , Zhang S C , et al . J . Chem. Eng. , 2003 , 94 :121 —126
[13] 刘尧飞(Liu Y F) , 王新平(Wang X P) , 田福平(Tian F P) .催化学报(Chin. J . Catal . ) , 2004 , 25(9) : 721 —726
[14] Madeira L M, Portela M F. Appl . Catal . A: General , 2005 ,281 : 179 —189
[15] Madeira L M, Martín-Aranda R M, Maldonado-Hódar F J , et al .J . Catal . , 1997 , 169 : 469 —479
[16] Vrieland G E , Murchison C B. Appl . Catal . A: General , 1996 ,134 : 101 —121
[17] Madeira L M, Portela M F , Mazzocchia C , et al . Catal . Today ,1998 , 40 : 229 —243
[18] Marcu I C , Sandulescu I , Millet J M M. J . Mol . Catal . A:Chem. 2003 , 203 : 241 —250
[19] Marcu I C , Sandulescu I , Millet J M M. Appl . Catal . A:General , 2002 , 227 : 309 —320
[20] Abdelouahad KA , Roullet M, Brun M, et al . Appl . Catal . A:General , 2001 , 210 : 121 —136
[21] Carrara C , Irusta S , Lombardo E , et al . Appl . Catal . A:General , 2001 , 217 : 275 —286
[22] Al2Zahrani S M, Elbashir N O , Abasaeed A E , et al . Catal .Lett . , 2000 , 69 : 65 —70
[23] Marcu I C , Millet J M M, Herrmann J M. Catal . Lett . , 2002 ,78 : 273 —279
[24] Uddin M A , Komatsu T , Yashima T. Chem. Lett . , 1993 ,1037 —1038
[25] Huff M, Schmidt L D. J . Catal . , 1995 , 155 : 82 —94
[26] Bocanegra S A , Castro A A , Guerrero-Ruíz A , et al . J . Chem.Eng. , 2006 , 118 : 161 —166
[27] McNamara J M, Jackson S D , Lennon D. Catal . Today , 2003 ,81 : 583 —587
[28] Larese C , Campos-Martin J M, Calvino J J , et al . J . Catal . ,2002 , 208 : 467 —478
[29] 徐天宏(Xu T H) , 匡文兴(Kuang W X) , 范以宁(Fan Y N) .无机化学学报(Journal of Inorganic Chemistry) , 1998 , 14 (3) :343 —346
[30] Bocanegra S A , Guerrero-Ruiz A , de Miguel S R , et al . Appl .Catal . A: General , 2004 , 277 : 11 —22
[31] Wu A. US 6 187 984 , 2001
[32] Wu A. US 6 198 012 , 2001
[33] Wu A. US 6 433 241 , 2002
[34] Cortright R D , Hill J M, Dumesic J A. Catal . Today , 2000 , 55 :213 —223
[35] 杨维慎(Yang W S) , 林励吾(Lin L W) , Berry F J . 分子催化(J . Mol . Catal . ) , 1991 , 5(3) : 209 —216
[36] Pirngruber G D , Seshan K, Lercher J A. J . Catal . , 1999 , 186 :188 —200
[37] Milas I , Nascimento M A C. Chem. Phys. Lett . , 2006 , 418 :368 —372
[38] Song Y Q , Zhu X X, Xu L Y. Catal . Commun. , 2006 , 7 :218 —233
[39] Lu J Y, Zhao Z , Xu C M, et al . J . Natrue Gas Chem. , 2005 ,14 : 1 —8
[40] Lu J Y, Zhao Z , Xu C M, et al . Catal . Commun. , 2006 , 7 :199 —203
[41] Lu J Y, Zhao Z , Xu CM, et al . Catal . Letter , 2006 , 109 : 65 —70
[42] 张一卫( Zhang Y W) , 周钰明( Zhou Y M) , 邱安定(Qiu A D) . 物理化学学报(Acta. Phys. -Chem. ) , 2006 , 22 (6) :672 —678
[43] Zhang Y W, Zhou Y M, Yang K Z , et al . Microporous and Mesoporous Materials , 2006 , 96 : 245 —254
[44] Zhang Y W, Zhou Y M, Qiu A D , et al . Catal . Commun. ,2006 , 7 : 860 —866
[45] Zhang Y W, Zhou Y M, Qiu A D , et al . Ind. Eng. Chem.Res. , 2006 , 45(7) : 2213 —2219
[46] Zhang Y W, Zhou Y M, Li Y, et al . Catal . Commun. , 2007 , 8 :1009 —1016
[47] Kwon H , Thompson L T , Eng J , et al . J . Catal . , 2000 , 190 :60 —68
[48] Neylon M K, Choi S , Kwon H , et al . Appl . Catal . A: General ,199 : 253 —262
[49] 葛善海(Ge S H) , 刘长厚(Liu C H) , 范煜(Fan Y) . 催化学报(Chin. J . Catal . ) , 2000 , 21(5) : 484 —488
[50] Assabumrungrat S , Rienchalanusarn T , Praserthdam P , et al . J .Chem. Eng. , 2002 , 85 : 69 —79
[51] Alfonso M J , Menéndez M, Santamaría J . J . Chem. Eng. , 2002 ,90 : 131 —138
[52] Téllez C , Menéndez M, Santamaría J . J . Catal . , 1999 , 183 :210 —211
[53] 葛善海(Ge S H) , 刘长厚(Liu C H) , 范煜(Fan Y) . 高校化学工程学报( Journal of Chemical Engineering of Chinese Universities) , 2001 , 15(3) : 230 —235
[54] Rubio O , Herguido J , Menéndez M. Chem. Eng. Sci . , 2003 ,58 : 4619 —4627
[55] 李丽(Li L) , 阎子峰( Yan Z F) . 化学进展( Prog. Chem. ) ,2005 , 17(4) : 651 —659
[56] 陆江银(Lu J Y) , 赵震(Zhao Z) , 徐春明(Xu C M) . 第十届全国青年催化学术会议论文集(Symposium of 10th National Youth Congress on Catalysis) . 呼和浩特, 2005. 383 —384
[1] Jiaye Li, Peng Zhang, Yuan Pan. Single-Atom Catalysts for Electrocatalytic Carbon Dioxide Reduction at High Current Densities [J]. Progress in Chemistry, 2023, 35(4): 643-654.
[2] Yuewen Shao, Qingyang Li, Xinyi Dong, Mengjiao Fan, Lijun Zhang, Xun Hu. Heterogeneous Bifunctional Catalysts for Catalyzing Conversion of Levulinic Acid to γ-Valerolactone [J]. Progress in Chemistry, 2023, 35(4): 593-605.
[3] Chunyi Ye, Yang Yang, Xuexian Wu, Ping Ding, Jingli Luo, Xianzhu Fu. Preparation and Application of Palladium-Copper Nano Electrocatalysts [J]. Progress in Chemistry, 2022, 34(9): 1896-1910.
[4] Qi Qi, Peizhu Xu, Zhidong Tian, Wei Sun, Yangjie Liu, Xiang Hu. Recent Advances of the Electrode Materials for Sodium-Ion Capacitors [J]. Progress in Chemistry, 2022, 34(9): 2051-2062.
[5] Bin Jia, Xiaolei Liu, Zhiming Liu. Selective Catalytic Reduction of NOx by Hydrogen over Noble Metal Catalysts [J]. Progress in Chemistry, 2022, 34(8): 1678-1687.
[6] Shiying Yang, Danyang Fan, Xiaojuan Bao, Peiyao Fu. Modification Mechanism of Zero-Valent Aluminum by Carbon Materials [J]. Progress in Chemistry, 2022, 34(5): 1203-1217.
[7] Mingjue Zhang, Changpo Fan, Long Wang, Xuejing Wu, Yu Zhou, Jun Wang. Catalytic Reaction Mechanism for Hydroxylation of Benzene to Phenol with H2O2/O2 as Oxidants [J]. Progress in Chemistry, 2022, 34(5): 1026-1041.
[8] Shujin Shen, Cheng Han, Bing Wang, Yingde Wang. Transition Metal Single-Atom Electrocatalysts for CO2 Reduction to CO [J]. Progress in Chemistry, 2022, 34(3): 533-546.
[9] Bolin Zhang, Shengyang Zhang, Shengen Zhang. The Use of Rare Earths in Catalysts for Selective Catalytic Reduction of NOx [J]. Progress in Chemistry, 2022, 34(2): 301-318.
[10] Wu Qiaomei, Yang Qiyue, Zeng Xianhai, Deng Jiahui, Zhang Liangqing, Qiu Jiarong. Catalytic Conversion of Cellulose-Based Biomass to Diols [J]. Progress in Chemistry, 2022, 34(10): 2173-2189.
[11] Bai Wenji, Shi Yubing, Mu Weihua, Li Jiangping, Yu Jiawei. Computational Study on Cs2CO3-Assisted Palladium-Catalyzed X—H(X=C,O,N, B) Functionalization Reactions [J]. Progress in Chemistry, 2022, 34(10): 2283-2301.
[12] Yang Linyan, Guo Yupeng, Li Zhengjia, Cen Jie, Yao Nan, Li Xiaonian. Modulation of Surface and Interface Properties of Cobalt-Based Fischer-Tropsch Synthesis Catalyst [J]. Progress in Chemistry, 2022, 34(10): 2254-2266.
[13] Yuan Su, Keming Ji, Jiayao Xun, Liang Zhao, Kan Zhang, Ping Liu. Catalysts for Catalytic Oxidation of Formaldehyde and Reaction Mechanism [J]. Progress in Chemistry, 2021, 33(9): 1560-1570.
[14] Xuechuan Wang, Yansong Wang, Qingxin Han, Xiaolong Sun. Small-Molecular Organic Fluorescent Probes for Formaldehyde Recognition and Applications [J]. Progress in Chemistry, 2021, 33(9): 1496-1510.
[15] Zhao Ding, Weijie Yang, Kaifu Huo, Leon Shaw. Thermodynamics and Kinetics Tuning of LiBH4 for Hydrogen Storage [J]. Progress in Chemistry, 2021, 33(9): 1586-1597.