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Progress in Chemistry 2007, Vol. 19 Issue (05): 805-812 Previous Articles   Next Articles

• Review •

Molecular Recognition in Aqueous Media with Molecular Imprinting Technique

Wang Xuejun, Xu Zhenliang*; Yang Zuoguo;Bing Naici   

  1. Membrane Science and Engineering R&D Center, Chemical Engineering Research Center, East China University of Science and Technology, Shanghai 200237, China
  • Received: Revised: Online: Published:
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Among the variety of biomimetic recognition systems based on supramolecular approaches, molecularly imprinted polymers (MIPs) have proven their potential as synthetic receptors receiving more and more attention. Conventional molecular imprinting technology allows the synthesis in organic solvents of molecularly imprinted polymers selective toward relatively low molecular weight compounds. However, synthesis in aqueous media of chemically and mechanically stable MIPs that can recognize biomolecules still is a great challenge. From small molecules to biomacromolecules, from organic phase to aqueous media, the application field expands with the development of molecular imprinting technique. The recent progress in preparation and recognition of molecularly imprinted polymers in aqueous phase are overviewed and discussed. The design strategy and preparation methods of aqueous MIPs are investigated. The emphasis is put on the applications of aqueous recognition in the fields of solid phase extraction, chromatographic stationary phases, drug delivery and controlled release, separation of active ingredients from herbs and recognition of biomolecules. The methods to improve the selectivities of MIPs in aqueous recognition are presented, and the challenges, as well as the suggestions to the development of molecular imprinting technique are outlined.
Key words: molecular imprinting, recognition in aqueous media, molecularly imprinted polymers, molecularly imprinted membrane

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