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Progress in Chemistry 2007, Vol. 19 Issue (05): 787-795 Previous Articles   Next Articles

• Review •

Preparation and Properties of Nanocomposites of Polyaniline and Metal Nanoparticles

Li Xingui;Sun Jin;Huang Meirong*   

  1. Key Laboratory of Advanced Civil Engineering Materials, College of Material Science and Engineering, Tongji University, Shanghai 200092，China
  • Received: Revised: Online: Published:
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Polyaniline/metal nanoparticle composites，a kind of novel materials developed in recent years, have been systematically reviewed from the history, preparation and multi-functionalities based on our recent research and the latest literature. The technique of introducing metal nanoparticle into polyaniline matrix could be summarized in three categories：in-situ compound, direct blending and layer-by-layer self-assembly. The resulted hybrids from organic polyaniline and inorganic metals not only retain the original respective intrinsic performance, but also exhibit coadjutant effect that is beneficial for improving the properties of polyaniline matrix in composites. The maximal conductivity of the composite is ca.100 times higher than that of the matrix, and the maximal peak current of oxidation is ca.10 times higher than that of the matrix. Traces of platinum microparticles dispersed in polyaniline film could result in a stable corrosion potential of stainless steel within the passive range. The unique properties of polyaniline/metal nanoparticle composites including outstanding intrinsically electrical conductivity, excellent reactive catalysis and powerful anticorrosion properties make them lie in few high performance composites. They have shown attractive potential in applications.
Key words: polyaniline, noble metals, metal nanoparticle, nanocomposites, catalytic activity

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