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Progress in Chemistry 2007, Vol. 19 Issue (05): 651-658 Previous Articles   Next Articles

• Review •

Studies and Applications of Catalytic Hydrogenolysis of Glycerol

Feng Jian;Yuan Maolin;Chen Hua*;Li Xianjun   

  1. Key Laboratory of Green Chemistry and Technology, Ministry of Education, Institute of Homogeneous Catalysis, College of Chemistry, Sichuan University, Chengdu 610064, China
  • Received: Revised: Online: Published:
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Because of the rapid development of biodiesel production by transesterification of vegetable oils and animal fats, large quantities of glycerol are formed as a reaction by-product. Seeking new utilization for the superfluous glycerol will improve the economy of the whole biodiesel production process. The studies of catalytic hydrogenolysis of glycerol have greatly increased in recent years, while no corresponding research has been reported in China. In this paper, the recent advances in catalytic hydrogenolysis of glycerol(1,2-propanediol,1,3-propanediol and ethylene glycol) are reviewed. The background of the studies of hydrogenolysis of glycerol is introduced. Then, emphases are focused on the reaction mechanisms (including the dehydration-hydrogenation mechanism,dehydrogenation-hydrogenation mechanism and chelation mechanism) and the application of catalytic hydrogenolysis of glycerol to glycols.The developing prospect of this research is also forecasted.
Key words: glycerol, catalytic hydrogenolysis, 1, 2-propanediol, 1, 3-propanediol, ethylene glycol

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