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Progress in Chemistry 2007, Vol. 19 Issue (05): 643-650 Previous Articles   Next Articles

• Review •

Direct Oxidation of Propane to Acrylic Acid over MoVTe(Sb)Nbo Mixed Metal Oxide Catalysts

Yang Xiujuan;Feng Ruming;Li Li;Ji Weijie**; Chen Yi   

  1. Key Laboratory of Mesoscopic Chemistry, MOE, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China
  • Received: Revised: Online: Published:
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The direct oxidation of propane to acrylic acid has become a hot spot in catalytic oxidation of light alkanes in recent years. The MoVTe(Sb)NbO mixed metal oxide catalysts are the most important catalysts for this reaction. This article intends to review recent progresses in preparation methodologies and in understanding vital crystalline structures which are closely related to catalytic performance. The latest knowledge on the functions of the constituent main elements in the catalysts is summarized in terms of the reaction pathway of propane oxidation. It is recognized that modification of particle size and morphology, phase composition and structure, surface acidity and redox property of catalyst are critical to achieve superb catalyst performance and stability.
Key words: propane, direct oxidation, mixed metal oxide catalysts, acrylic acid

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