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Progress in Chemistry 2007, Vol. 19 Issue (0203): 350-355 Previous Articles   Next Articles

• Review •

Metal-Free Initiator /Catalyst Systems for the Ring Opening Polymerization of Cyclic Ester Monomers

Liu Jiyan1,2; Zhang Liming2**   

  1. 1. School of Chemistry and Environmental Engineering, Jianghan University, Wuhan 430056,China;
    2. School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275,China
  • Received: Revised: Online: Published:
  • Contact: Zhang Liming
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The ring opening polymerization (ROP) of cyclic ester monomers in the presence of various initiator/catalyst systems is a main approach for the preparation of biodegradable aliphatic polyesters. The recent progress of metal-free initiator/catalyst systems used for the ROP of cyclic ester monomers is reviewed, including H2O, alcohol, amine and carboxylic acid initiators, as well as proton acid, phosphine, N-heterocycle catalysts.
Key words: cyclic ester monomers, ring opening polymerization, metal-free initiators, catalysts, aliphatic polyesters

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