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Progress in Chemistry 2007, Vol. 19 Issue (0203): 234-242 Previous Articles   Next Articles

• Review •

Transition Metal Sulfides Catalysts: Active Phase Structure and Mechanism of the Catalytic Reaction

Chai Yongming; An Gaojun;Liu Yunqi;Liu Chenguang**   

  1. State Key Laboratory of Heavy Oil Processing, Key Laboratory of Catalysis, China National Petroleum Corporation, College of Chemistry & Chemical Engineering,China University of Petroleum,Dongying 257061, China，
  • Received: Revised: Online: Published:
  • Contact: Liu Chenguang
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The supported catalysts of transition metal sulfides (TMS) are applied in the petroleum refining processes extensively. In order to aid the development of catalysts for hydrodesulfurization (HDS), there has been a strong emphasis in the past on establishing fundamental relationships between the structure of the catalyst and the HDS activity. In this paper, the progress of research is reviewed from two aspects ： the structure of the active phase and the mechanism of adsorption-to-reaction of reactants on the active sites on the surface of TMS catalysts.The controversies in the research of catalysis of transition metal sulfides and the directions in the future are also propounded.
Key words: transition metal sulfides(TMS), catalysis mechanism, active phase, hydrodesulfurization(HDS)

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[ 1 ] Choi J , MaugéF , Uzio D , et al . Appl . Catal . A: General ,2004 , 267 (1/2) : 203 —216
[ 2 ] Hubaut R , Poulet O , Grimblot J , et al . J . Mol . Catal . , 1993 ,81(2) : 301 —310
[ 3 ] Lombardo E A , Houalla M, Hall W K. J . Catal . , 1978 , 51(2) :256 —268
[ 4 ] Song C , Ma X. Appl . Catal . B , 2003 , 41(1/2) : 207 —238
[ 5 ] Steven W M, Nick J G. NPRN Annual Meeting , 2002
[ 6 ] Silvy R P. Appl . Catal . A , 2004 , 261 (2) : 247 —252
[ 7 ] Brune M, Reimert R. Ind. Eng. Chem. Res. , 2005 , 44 (25) :9691 —9694
[ 8 ] Ferdous D , Dalai A K, Adjaye J . Ind. Eng. Chem. Res. ,2006 , 45(2) : 544 —552
[ 9 ] Kabe T , Ishihara A , Otsuki S , et al . Ind. Eng. Chem. Res. ,1997 , 36(12) : 5146 —5152
[10] Sergio R , Carmen C M, Pedro V , et al . Petrol . Sci . Tech. ,2004 , 22(1/2) : 189 —199
[11] Dan Y, Chaim A. AIChE J . , 1977 , 23(3) : 342 —346
[12] Gioia F , Lee V. Ind. Eng. Chem. Proc. Des. Dev. , 1986 , 25(4) : 918 —925
[13] Furimsky E. Catal . Rev. Sci . Eng. , 2005 , 47(3) : 297 —489
[14] Prins R. Adv. Catal . , 2001 , 46 : 399 —464
[15] Bej S K, Dalai A K, Adjaye J . Energy & Fuels , 2001 , 15 (2) :377 —383
[16] Park Y C , Oh E S , Rhee H K. Ind. Eng. Chem. Res. , 1997 ,36(12) : 5083 —5089
[17] Cattenot M, Portefaix J L , Afonso J , et al . J . Catal . , 1998 , 173(2) : 366 —373
[18] Rota F , Ranade V S , Prins R. J . Catal . , 2001 , 200(2) : 389 —399
[19] Anabtawi J A , Mann R S , Khulbe K C. J . Catal . , 1980 , 63(2) : 456 —462
[20] Teh C. Energy &Fuels , 1994 , 8(5) : 1149 —1151
[21] Brammer S T , Weller S W. Fuel Proc. Tech. , 1979 , 2 (2) :155 —159
[22] Chien P L , Sellers G M, Weller S W. Fuel Proc. Tech. , 1983 ,7 (1) : 1 —9
[23] Belma D , Wendell H W. Fuel Proc. Tech. , 1997 , 53 (1/2) :157 —169
[24] Sapre A V , Gates B C. Ind. Eng. Chem. Proc. Des. Dev. ,1982 , 21(1) : 86 —94
[25] Yamagata N , Owada Y, Okazaki S , et al . J . Catal . , 1977 , 47(3) : 358 —363
[26] 胡永康(Hu Y K) , 葛再贵( Ge Z G) , 韩崇仁(Han C R) 等.石油炼制与化工( Petroleum Processing and Petrochemicals) ,1994 , 25(11) : 50 —56
[27] 李大东(Li D D) . 石油学报(石油加工) (Acta Petrolei Sinica ,Petroleum Processing Section) , 2005 , 21(3) : 17 —24
[28] Botchwey C , Dalai A K, Adjaye J . Energy & Fuels , 2003 , 17(5) : 1372 —1381
[29] Arnaldo C F , Santos A C B. Catal . Today , 2006 , 118 (3/4) :402 —409
[30] Speight J G. Catal . Today , 2004 , 98(1P2) : 55 —60
[31] 王化国(Wang H G) . 石油炼制与化工( Petroleum Processing and Petrochemicals) , 2001 , 32(6) : 21 —24
[32] Kagami N , Vogelaar B M, Moulijn J A , et al . Appl . Catal . A ,2005 , 293 : 11 —23
[33] Macaud M, Milenkovic A , Schulz E , et al . J . Catal . , 2000 ,193 : 255 —263
[34] Nag N K, Sapre A V , Broderick D H , et al . J . Catal . , 1979 ,57 : 509 —512
[35] Houalla M, Broderick D H , Sapre A V , et al . J . Catal . , 1980 ,61 : 523 —527
[36] Bataille F , Lemberton J L , Michaud P , et al . J . Catal . , 2000 ,191(1) : 409 —422
[37] Kabe T , Zhang Q. Appl . Catal . A , 1993 , 97 : L1 —L9
[38] Kwart H , Schuit G C A , Gates B C. J . Catal . , 1980 , 61 : 128 —134
[39] Singhal G H , Espino R L , Sobel J E. J . Catal . , 1981 , 67 :446 —456
[40] Shafi R , Hutching GJ . Catal . Today , 2000 , 59 : 423 —442
[41] Houalla M, Nag N K, Sapre A V , et al . AICHE J . , 1978 , 24(6) : 1015 —1021
[42] Nagal M, Sato T , Aiba A. J . Catal . , 1986 , 97 : 52 —58
[43] 刘晨光(Liu C G) , Flora T T N. 催化学报(Chinese Journal of Catalysis) , 1999 , 20(5) : 499 —504
[55] Laredo G C , Altamirano E , de los Reyes J A. Appl . Catal . A ,2003 , 242 (2) : 311 —320
[56] Van Gestel J , Dujardin C , Mauge F , et al . J . Catal . , 2001 , 202(1) : 78 —88
[57] Prins R , Jian M, Flechsenhar M. Polyhedron , 1997 , 16 (18) :3235 —3246
[58] Styliani C K, Richard M. Ind. Eng. Chem. Res. , 1995 , 34(1) : 101 —117
[59] Sapre A V , Gates B C. Ind. Eng. Chem. Proc. Des. Dev. ,1981. 20 (1) : 68 —73
[60] Tops?e H , Clausen B S , Tops?e N Y. Ind. Eng. Chem.Fundam. , 1986 , 25 : 25 —36
[61] Tops?e H , Tops?e N. J . Catal . , 1983 , 84 : 386 —392
[62] Tops?e H , Clausen B S. Catal . Rev. Sci , Eng. , 1984 , 26 (3/4) : 395 —420
[63] Tops?eH , Clausen B S , Tops?e N Y, et al . Stud. Surf . Sci .Catal . , 1990 , 53 : 77 —83
[64] Tops?e H , Candia R , Tops?e N Y, et al . Bull . Soc. Chim.Belg. , 1984 , 93 : 783 —791
[65] Clausen B S , M? rup S , Tops?e H , et al . J . Physique , 1976 , 37 :249 —257
[66] Clausen B S , Tops?e H , Candia R , et al . J . Phys. Chem. ,1981 , 85(25) : 3868 —3872
[67] Tops?e H , Clausen B S , Candia R , et al . J . Catal . , 1981 , 68 :433 —452
[68] Wiverl C , Candia R , Clausen B S , et al . J . Catal . , 1981 , 68 :453 —463
[69] Kabe T , Qian W H , Ishihara A. J . Catal . , 1994 , 149 : 171 —180
[70] Kabe T , Qian W H , Ishihara A. J . Phys. Chem. , 1994 , 98(3) : 912 —916
[71] Qian W H , Ishihara A , Wang G D , et al . J . Catal . , 1997 , 170 :286 —294
[72] Qian W H , Zhang Q , Okoshi Y, et al . J . Chem. Soc. Faraday Trans. , 1997 , 93(9) : 1821 —1826
[73] Qian W H , Okoshi Y, Ishihara A , et al . J . Chem. Soc. Faraday Trans. , 1997 , 93(24) : 4395 —4400
[74] Kabe T , Qian W H , Wang G D , et al . Catal . Today , 1996 , 29 :197 —202
[75] Qian W H , Ishihara A , Ogawa S , et al . J . Phys. Chem. , 1994 ,98 : 907 —911
[76] Kabe T , Qian W H , Ogawa S , et al . J . Catal . , 1993 , 143 :239 —248
[77] Wang A , Wang Y, Kabe T , et al . J . Catal . , 2001 , 199 : 19 —29
[78] Crajé M W J , de Beer V H J , van Veen J A R , et al . Appl .Catal . A , 1993 , 100 : 97 —109
[79] Lipsch J , Schuit G C. J . Catal . , 1969 , 15(2) : 163 —167
[80] Lipsch J , Schuit G C. J . Catal . , 1969 , 15(2) : 174 —178
[81] Lipsch J , Schuit G C. J . Catal . , 1969 , 15(2) : 179 —189
[82] Schuit G C A , Gates B C. AIChE J . , 1973 , 19(3) : 417 —438
[83] Voorhoeve R J H. J . Catal . , 1971 , 23(2) : 236 —242
[84] Voorhoeve R J H , Stuiver J C M. J . Catal . , 1971 , 23 : 228 —235
[85] Frragher A L , Cossee P. Proc. 5th Int . Cong. Catal . ( ed.Hightower J W) . Amsterdam: North Holland , 1973. 1301 —1305
[86] Farragher A L. Advances in Coll . Int . Sci . , 1979 , 11(1) : 3 —41
[87] Karroua M, Matralis H , Grange P , et al . J . Catal . , 1993 , 139 :371 —374
[88] Delmon B. International Chem. Eng. , 1980 , 20(4) : 639 —641
[89] Asua J M, Delmon B. Appl . Catal . , 1984 , 12(2) : 249 —262
[90] Delmon B. Benelux Metall , 1981 , 2 : 285 —294
[91] Fierro J L G, Grange P , Delmon B. Preprints : Division of Petroleum Chemistry , ACS , 1987 , (1/2) : 287 —290
[92] Portela L , Grange P , Delmon B. J . Catal . , 1995 , 156 ( 2) :243 —254
[93] Grange P , Vanhaeren X. Catal . Today , 1997 , 36 : 375 —391
[94] Karroua M, Grange P , Delmon B. Appl . Catal . , 1989 , 50 :L5 —L10
[95] Karroua M, Centeno A , Matralis H K, et al . Appl . Catal . ,1989 , 51 : L21 —L26
[96] Escalona N , Garcia R , Lagos G, et al . Catal . Commun. , 2006 ,7 (12) : 1053 —1056
[97] Baeza P , Ureta-Zanartu M S , Delmon B , et al . Appl . Catal . A ,2004 , 274 (1P2) : 303 —309
[98] Ojeda J , Escalona N , Baeza P , et al . Chem. Commun. , 2003 ,1608 —1609
[99] Louwers S P A , Craje M W J , van der Kraan A M, et al . J .Catal . , 1993 , 144 : 579 —596
[100] Bouwens S M A M, van Zon F B M, van Dijk M P , et al . J .Catal . , 1994 , 146 : 375 —393
[101] Ramirez J , Fuentes S , Diaz GV M, et al . Appl . Catal . , 1989 ,52 : 211 —223
[102] Eijsbouts S. Appl . Catal . A , 1997 , 158 : 53 —92
[103] Dugulan A I , Crajé M W J , Kearley GJ , et al . J . Catal . , 2005 ,229(2) : 276 —282
[104] Louwers S P A , Prins R. J . Catal . , 1992 , 133 : 94 —111
[105] Louwers S P A , Prins R. J . Catal . , 1993 , 139 : 525 —539
[106] 李大东(Li D D) , 侯莹(Hou Y) , 石亚华(Shi Y H) 等. CN 1085 934A , 1994
[107] 赵壁英(Zhao B Y) , 徐献平(Xu X P) , 陆林(Lu L) 等. 石油化工(Petrochemical Technology) , 1993 , 22(4) : 216 —229
[108] Saini A R , Johnson B G, Massoth F E. Appl . Catal . , 1988 , 40(1/2) : 157 —172
[109] Thomas H , Cáceres C , Blanco M. J . Chem. Soc. Faraday Trans. , 1994 , 90(14) : 2125 —2131
[110] Wei Z B , Xin Q , Guo X, et al . Appl . Catal . , 1990 , 63 (2) :305 —317
[111] 傅贤智(Fu X Z) , 杨锡尧(Yang X R) , 庞礼(Pang L) . 燃料化学学报(Journal of Fuel Chemistry and Technology) , 1989 , 17(4) : 289 —295
[112] Damyanova S , Spojakina A , Jiratova K. Appl . Catal . A , 1995 ,125 : 257 —269
[113] 建谋(Jian M) , 石亚华(Shi Y H) , 李大东(Li D D) . 石油学报( 石油加工) (Acta Petrolei Sinica , Petroleum Processing Section) , 1991 , 7(3) : 28 —34
[114] 建谋(Jian M) , 杨先春(Yang X C) , 石亚华(Shi Y H) 等. 分子催化(Journal of Molecular Catalysis) , 1990 , 4(3) : 181 —185
[115] Ramirez J , Cuevas R , López A , et al . Appl . Catal . , 1990 , 57 :223 —240
[116] Chen Y W, Tsai M C , Li C P. Ind. Eng. Chem. Res. , 1994 ,33(9) : 2040 —2046
[117] Clausen B S , Niemann W, Zeuthen P , et al . Preprints : Division of Petroleum Chemistry , ACS , 1990 , 35(2) : 208 —210
[118] Zeuthen P , Blom P , Muegge B , et al . Appl . Catal . , 1991 , 68 :117 —130
[119] Morales A , de Agudelo M M R. Appl . Catal . , 1986 , 23 : 23 —34
[120] Ramírez J , Castaìo V M, Leclercq C , et al . Appl . Catal . A ,1992 , 83 : 251 —261
[121] Eusbouts S , van Gestel J N M, van Veen J A R , et al . J .Catal . , 1991 , 131 : 412 —432
[122] Breysse M, Portefaix J L , Vrinat M. Catal . Today , 1991 , 10 :489 —505
[123] Maity S K, Rana M S , Bej S K, et al . Appl . Catal . A , 2001 ,205 : 215 —225
[124] Afanasiev P , Thiollier A , Breysse M, et al . Top. Catal . , 1999 ,8 (3/4) : 147 —160
[125] Afanasiev P , Geantet C , Breysse M. J . Catal . , 1995 , 153 : 17 —24
[126] Afanasiev P , Cattenot M, Geantet C , et al . Appl . Catal . A ,2002 , 237 : 227 —237
[127] Afanasiev P , Geantet C , Breysse M. J . Catal . , 1996 , 162 :143 —146
[128] Hiroshima K, Honma T , Yamada M, et al . Appl . Surf . Sci . ,1997 , 121 : 433 —436
[129] Medici L , Prins R. J . Catal . , 1996 , 163 (1) : 38 —49
[130] Van de Water L G A , Bergwerff J A , Leliveld R G, et al . J .Phys. Chem. B , 2005 , 109 (30) : 14513 —14522
[131] Breysse M, Christophe G, Michel V , et al . Catal . Today , 2003 ,86(1/4) : 5 —16
[132] 刘晨光(Liu C G) , 柴永明(Chai Y M) , 赵会吉(Zhao HJ) 等.CN 10 039 44915 , 2004
[133] Chai Y M, Liu Y Q , Liu C G. Prepr . Pap. Am. Chem. Soc. ,Div. Pet . Chem. , 2005 , 50(1) : 90 —92
[134] Tops?e H , Clausen B S. Appl . Catal . , 1986 , 25 : 273 —293
[135] Jose2Yacaman M, Chianelli R R. Adv. Hydrotreating Catal . ,1994 , 39(4) : 575 —583
[136] Daage M, Chianelli R R. J . Catal . , 1994 , 149 : 414 —427
[137] Chianelli R R , Daage M, Ledoux MJ . Adv. Catal . , 1994 , 40 :177 —232
[138] Helveg S , Lauritsen J V , Tops?e H , et al . Phy. Rev. Letters ,2000 , 84(5) : 951 —954
[139] Lauritsen J V , Clausen B S , Tops?e H , et al . J . Catal . , 2001 ,197(1) : 1 —5
[140] Lauritsen J V , Bollinger MV , Tops?e H , et al . J . Catal . , 2004 ,221(2) : 510 —522
[141] Lauritsen J V , N?rskov J K, Tops?e H , et al . J . Catal . , 2004 ,224(1) : 94 —106
[142] Lauritsen J V , Vang R T , Besenbacher F. Catal . Today , 2006 ,111(1/2) : 34 —43
[143] ByskovL S , N?rskov J K, Tops?e H , et al . J . Catal . , 1999 , 187(1) : 109 —122
[144] Kabe T , Qian W H , Tanihata K, et al . J . Chem. Soc. Faraday Trans. , 1997 , 93(20) : 3709 —3713
[145] Qian W H , Hachiya Y, Wang D , et al . Appl . Catal . A , 2002 ,227 :19 —28
[146] Wang D , Qian W H , Ishihara A , et al . Appl . Catal . A , 2002 ,224 : 191 —199
[147] 王锦业(Wang J Y) , 聂红(Nie H) , 李大东(Li D D) 等. 催化学报(Chinese Journal of Catalysis) , 1999 , 20(5) : 541 —543
[148] Alias M O , Srinivasan V. Indian J . Chem. , 1990 , 29A: 624 —629
[149] Duchet J C , van Oers E M, de Beer V H J , et al . J . Catal . ,1983 , 80 : 386 —394
[150] Cornelis K G, Vincentius H , Prins R , et al . Ind. Eng. Chem.Prod. Res. Dev. , 1986 , 25(4) : 522 —530
[151] Vissers J P R , Lensing TJ , de Beer V HJ . Appl . Catal . , 1987 ,30(1) : 21 —31
[152] Prins R , de Beer V H J , Somorjai GA. Catal . Rev. Sci . Eng. ,1989 , 31(1/2) : 1 —41
[153] Arnoldy P , van den J A M, Moulijn J A. J . Catal . , 1985 , 92 :35 —55
[154] Weber T , Muijsers J C , Niemantsverdriet J W. J . Phys. Chem. ,1996 , 100 : 14144 —14150
[155] Kishan G, Coulier L , de Beer V H J , et al . J . Catal . , 2000 ,196 : 180 —189
[156] Kooyman P J , Buglass J G, Reinhoudt H R , et al . J . Phys.Chem. B , 2002 , 106 : 11795 —11799
[157] Reinhoudt H R , Troost R , van Langeveld A D , et al . J . Catal . ,2001 , 203 : 509 —515
[158] Hensen E J M, Kooyman P J , van der Meer Y, et al . J . Catal . ,2001 , 199 : 224 —235
[159] Vradman L , Landau M V , Herskowitz M, et al . J . Catal . , 2003 ,213 : 163 —175
[160] Soled S L , Miseo S , Riley K L , et al . US 6 299 760 , 2001
[161] Huirache A R , Albiter M A , Martinez S R , et al . Adv. Tech.Mat . Mat . Proc. , 2006 , 8(2) : 140 —145
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