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Progress in Chemistry 2007, Vol. 19 Issue (0203): 225-233 Previous Articles   Next Articles

• Review •

Nonmeatl Element Doping Mechanisms of Titanium Oxide Photocatalyst

Tang Yuchao1,2**; Huang Xianhuai2; Yu Hanqing1; Hu Chun3   

  1. 1. School of Chemistry and Materials Science, University of Science and Technology of China, Hefei, 230026, China;
    2. School of Environmental Engineering, Anhui Institute of Architecture and Industry, Hefei, 230022, China;
    3. Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing, 100085, China
  • Received: Revised: Online: Published:
  • Contact: Tang Yuchao
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In order to obtain visible light response, doping or modifying titania by nonmetal elements such as nitrogen has been investigated extensively in recent years. In this paper, recent progress in mechanism of titania doping by nitrogen, carbon, sulphur, fluorine is reviewed. Methods for preparing nitrogen doped titania are follows: i) reduce titania by ammonia gas under high temperature; ii) sputter titania target in nitrogen gas; iii)pulsed laser deposition in nitrogen gas; iv) mechanochemica1 process titania in ammonia condition; v)direct oxidation titanic nitrogen; vi)forming organic titanic nitride and then thermal treated it; vii)hydrolysis a titanic precursor in ammonia solution then thermal treated the precipitate. Structure and the mechanism of visible light response of the nitrogen doped titania are discussed according to literature reports although there had many inconsistent conclusions. Narrowing the band gap of titania or forming a new isolated level in band gap may be the most probable reason for visible response. Titania doping by carbon, sulphur or fluorine can also give rise to visible light response and high photo efficiency, but there had many inconsistent conclusions too.
Key words: photocatalysis, titania, nonmetal elements, nitrogen, carbon, sulphur, fluorine

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