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Progress in Chemistry 2007, Vol. 19 Issue (01): 93-100 Previous Articles   Next Articles

• Review •

Gas/Particle Partitioning Theory for Secondary Organic Aerosol

Wang Zhenya**;  Hao Liqing ; Zhang Weijun   

  1. Laboratory of Environmental Spectroscopy, Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Science, Hefei, 230031,China
  • Received: Revised: Online: Published:
  • Contact: Wang Zhenya
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The paper reviews the gas/paticle pattitioning theory for secondary organic aerosol formation and describes its development and possible application.In atmosphere, semi-volatile organic compounds are formed through oxidation of certain gas-phase organic species and the secondary organic aerosol formation may be best described by a gas/particle partitioning absorption model. The process of gas/particle partitioning is dependent on both the composition, concentration and vapor pressure of semi- volatile species, and the concentration and composition of absorptive materials. On the basis of gas/particle partitioning theory, the thermodynamic model for gas/particle partitioning of molecular constituents has also been developed. This model can be used to predict the liquid water contents in aerosol, distributions of inorganic compounds and hydrophilic/hydrophobic organic compounds. The combination of the chemistry mechanism and the thermodynamic model for secondary organic aerosol formation with the California Institute of Technology(CIT)'s three-dimensional urban/regional atmospheric model could be used to perform comprehensive gas- and aerosol- phase simulations.
Key words: Secondary organic aerosol, gas/particle partitioning, thermodynamic model

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[ 1 ] Pun B K, Griffin R J , Seigneur C , et al . J . Geophysical Research , 2002 , 107 (D17) : art . no. 4333
[ 2 ] 蒋展鹏(Jiang Z P) , 祝万鹏( Zhu W P) . 环境工程监测(Environmental Engineering Monitoring) . 北京: 清华大学出版社(Beijing : Tsinghua University Press) , 1991. 349 —352
[ 3 ] Hornby A S , Gatenby E V , Wakefield H. 现代高级英汉双解辞典(Modern Advanced English-Chinese Dictionary ) . Hong Kong : Oxford University Press , 1978. 1225
[ 4 ] Odabasi M, Ongan O , Cetin E. Atmos. Environ. , 2005 , 39 :3763 —3770
[ 5 ] 沈学忧(Shen X Y) , 罗晓璐(Luo X L) , 朱利中(Zhu L Z) . 浙江大学学报(理学版) (Journal of Zhejiang University (Science Edition) ) , 2001 , 28 (4) : 547 —556
[ 6 ] Atkinson R. Atmos. Environ. , 2000 , 34 : 2063 —2101
[ 7 ] Nguyen K, Dabdub D. Aerosol Sci . Technol . , 2002 , 36 :560 —572
[ 8 ] Griffin R J , Dabdub D , Seinfeld J H. J . Geophysical Research ,2002 , 107 (D17) : art . no. 4332
[ 9 ] 王振亚(Wang Z Y) , 郝立庆(Hao L Q) , 张为俊( Zhang W J ) . 化学进展(Prog. Chem. ) , 2005 , 17 (4) : 732 —739
[10] Pankow J F. Atmos. Environ. , 1994 , 28 : 185 —188
[11] Pankow J F. Atmos. Environ. , 1994 , 28 : 189 —193
[12] Odum J R , Hoffmann T , Bowman F , et al . Environ. Sci .Technol . , 1996 , 30 : 2580 —2585
[13] Kroll J H , Seinfeld J H. Eviron. Sci . Technol . , 2005 , 39 :4159 —4165
[14] Odum J R , Jungkamp T P W, Griffin R J , et al . Science , 1997 ,276 : 96 —99
[15] Odum J R , Jungkamp T P W, Griffin R J , et al . Environ. Sci .Technol . , 1997 , 31 : 1890 —1897
[16] Odum J R , Jungkamp T P W, Griffin R J , et al . Science , 1997 ,276 : 96 —99
[17] Forstner H J L , Flagan R C , Seinfeld J H. Environ. Sci .Technol . , 1997 , 31 : 1345 —1358
[18] Bowman F M, OdumJ R , Seinfeld J H. Atmos. Environ. , 1997 ,31 : 3921 —3931
[19] Lazaridis M. J . Aerosol Sci . , 1999 , 39 : 1165 —1170
[20] Dachs J , Eisenreich S J . Environ. Sci . Technol . , 2000 , 34 :3690 —3697
[21] Bowman F M, Karalegos A M. Environ. Sci . Technol . , 2002 ,36 : 2701 —2707
[22] Offenberg J H , Baker J E. Atmos. Environ. , 2002 , 36 : 1205 —1220
[23] Lohmann R , Lammel G. Environ. Sci . Technol . , 2004 , 38 :3793 —3803
[24] Chandramouli B , Jang M, Kamens R M. Environ. Sci .Technol . , 2003 , 37 : 4113 —4121
[25] Shrivastava M K, Lipsky E M, Stanier C O , et al . Envirn. Sci .Technol . , 2006 , 40 : 2671 —2677
[26] PankowJ F , Seinfeld J H , Asher W E , et al . Environ. Sci .Technol . , 2001 , 35 : 1164 —1172
[27] Seinfeld J H , Asher W E , Erdakos G B , et al . Environ. Sci .Technol . , 2001 , 35 : 1806 —1817
[28] Griffin R J , Nguyen K, Dabdub D , et al . J . Atmos. Chem. ,2003 , 44 : 171 —190
[29] Griffin R J , Dabdub D , Kleeman M J , et al . J . Geophysical Research , 2002 , 107 (D17) : art . no. 4334
[30] Griffin R J , Dabdub D , Seinfeld J H. J . Geophysical Research ,2005 , 110 (D5) : art . no. D05304
[31] Meng Z Y, Dabdub D , Seinfeld J H. J . Geophysical Research ,1998 , 103 (D3) : 3419 —3435
[32] Zhang Y, Seigneur C , Seinfeld J H , et al . Atmos. Environ. ,2000 , 34 : 117 —137
[33] Kuhns H , Bohdan V , ChowJ C , et al . Atmos. Environ. , 2003 ,37 : 511 —524
[34] Fredenslund A , Gmehling J , Rasmussen P. Vapor-Liquid Equilibria Using UNIFAC: A Group2Contribution Method. New York : Elsevier Scientific Publishing , 1977. 1 —3
[35] Pankow J F. Atmos. Enviro. , 2003 , 37 : 3323 —3333
[36] Erdakous G B , Pankow J F. Atmos. Environ. , 2004 , 38 :1005 —1013
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