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Progress in Chemistry 2007, Vol. 19 Issue (01): 173-185 Previous Articles   Next Articles

• Review •

Application of ATR-FTIR Spectroscopy in Polymer Film Study

Jiang Yan;Shen Yi;Wu Peiyi**   

  1. The Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, Fudan University, Shanghai 200433, China
  • Received: Revised: Online: Published:
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Attenuated total reflectance (ATR) - FTIR is widely used due to its distinct advantage in studies of polymer films. Layer-by-layer assembly technique is a popular method to prepare ultrathin functional films. ATR-FTIR spectroscopy is introduced here to investigate the structural information of the multilayers without any damage to the samples. Besides, the diffusion process of small molecules, especially water molecules, in the polymer films may be studied carefully by means of ATR-FTIR spectroscopy accompanied by two-dimensional (2D) correlation spectroscopy as a useful tool. In this review, the principle and advantage of ATR-FTIR are briefly introduced and the applications of this effective method in the field of both layer-by-layer assembly technique and diffusion behavior of water molecules in polymer films are discussed.

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