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Progress in Chemistry 2007, Vol. 19 Issue (01): 153-158 Previous Articles   Next Articles

• Review •

Helically Chiral Polyacetylene Derivatives

Dai Jian1，2;Ha Chengyong1*;Chang Dongliang1 ;Shen Minmin1   

  1. 1. Key Laboratory of Cellulose and Lignocellulosics Chemistry,  Guangzhou Institute of Chemistry, Chinese Academy of Sciences, Guangzhou 510650, China; 2. Graduate School of the Chinese Academy of Sciences, Beijing 100039,  China
  • Received: Revised: Online: Published:
  • Contact: Ha Chengyong
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Polyacetylene (PA) is a symmetric chain of conjugated macromolecule, whose chain symmetry can, however, be broken by external and internal perturbations, generating helically chiral polymers. In this article, progress on syntheses and functions of helically chiral polyacetylene is reviewed. It is emphasized that helically chiral PA derivatives show various functional properties such as stimuli-response, chromism , photo- and electroluminescence, biomimetic structures, and molecular recognition etc, through simple external stimulate such as solvent, pH, temperature, additives etc.
Key words: polyacetylene(PA), helically chirality, asymmetric force field, tunable

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Abstract

Helically Chiral Polyacetylene Derivatives