中文
Earlier issues
Announcement
More
Progress in Chemistry 2007, Vol. 19 Issue (01): 145-152 Previous Articles   Next Articles

• Review •

Ring-Opening Polymerization of Ethylene Oxide and Propylene Oxide

Zhang Zhiguo**;Yin Hong   

  1. Department of Chemical and Biochemical Engineering, Zhejiang University, Hangzhou 310027, China
  • Received: Revised: Online: Published:
  • Contact: Zhang Zhiguo
PDF ( 7692 ) Cited
Export

EndNote

Ris

BibTeX

Polyether (primarily homopolymers and copolymers of ethylene oxide and propylene oxide) which has the properties of excellent surface activity, flexibleness of hydrophile-lipophile balance(HLB) and low toxicity has been widely used in surfactant and polyurethane industries. The progress in the catalytic ring-opening polymerization of ethylene oxide and propylene oxide is reviewed in this paper. The different catalytic mechanisms of cationic catalysts, anionic catalysts and coordination catalysts are discussed respectively. The application of coordination catalysts in the catalytic ring-opening polymerization is intensively introduced and the further research trends are pointed out.
Key words: ethylene oxide, propylene oxide, ring-opening polymerization, reaction mechanism, coordination catalysts

CLC Number: 

[ 1 ] 钱伯章(Qian B Z) . 化学推进剂与高分子材料(Chemical Propellants &Polymeric Materials) , 2004 , 2(6) : 51 —53
[ 2 ] 章文( Zhang W) . 化工科技市场( Chemical Technology Market) , 2003 , 26(12) : 5 —7
[ 3 ] 张骏(Zhang J ) . 中国洗涤用品工业(China Surfactant Soap and Detergent) , 2004 , (6) : 68 —70
[ 4 ] Burridge E. Eur. Chem. News , 2004 , 80(2095) : 17
[ 5 ] Burridge E. Eur. Chem. News , 2004 , 80(2100) : 15
[ 6 ] Xi Z W, Zhou N , Sun Y, Li KL. Science , 2001 , 292 : 1139 —1141
[ 7 ] 张治国(Zhang Z G) , 尹红(Yin H) , 陈志荣(Chen Z R) . 石油学报:石油加工(Acta Petrolei Sinica : Petroleum Processing Section) , 2005 , 21(1) : 31 —36
[ 8 ] 张治国(Zhang Z G) , 尹红(Yin H) , 陈志荣(Chen Z R) . 化学学报(Acta Chimia Sinica) , 2004 , 62(20) : 1988 —1992
[ 9 ] Odian G. Principles of Polymerization. 3rd ed. NY: John Wiley&Sons , 1991. 532 —558
[10] Worsfold D J , Eastham A M. J . Am. Chem. Soc. , 1957 , 79(4) : 897 —899
[11] Worsfold D J , Eastham A M. J . Am. Chem. Soc. , 1957 , 79(4) : 900 —902
[12] Kuran W. Prog. Polym. Sci . , 1998 , 23 : 919 —992
[13] Boileau S. Comprehensive Polymer Science (eds. Eastmond G C ,Ledwith A , Russo S , et al ) . London : Pergamon Press , 1989.467 —487
[14] 朱树新(Zhu S X) . 开环聚合(Ring-Opening Polymerization) .北京: 化学工业出版社(Beijing : Chemical Industry Press) ,1987. 47 —72
[15] 王梅(Wang M) , 魏秀贞(Wei X Z) , 黄鹏程(Huang P C)等. 化学世界(Chemical World) , 1997 , 38(2) : 59 —64
[16] Dege G J , Harris R L , Mackenzie J S. J . Am. Chem. Soc. ,1959 , 81(13) : 3374 —3379
[17] Pierre L E S , Price C C. J . Am. Chem. Soc. , 1956 , 78 (14) :3432 —3436
[18] Simons D M, Verbanee J J . J . Polym. Sci . , 1960 , 44 (144) :303 —311
[19] Steiner E C , Pelletier R R , Trucks R O. J . Am. Chem. Soc. ,1964 , 86(21) : 4678 —4686
[20] Gee G, Higginson W C E , Taylor K J , Trenholme M W. J .Chem. Soc. , 1961 , 4298 —4303
[21] Yang K, Nield GL , Washecheck P H. US 4 223 164 , 1980
[22] Yang K. US 4 239 917 , 1980
[23] Yang K, Nield GL , Washecheck P H. US 4 302 613 , 1981
[24] Yang K, Nield GL , Washecheck P H. EP 49 358 , 1982
[25] Yang K, Washecheck P H , Nield GL. EP 34 648 , 1981
[26] Yang K, Nield GL , Washecheck P H. EP 85 167 , 1983
[27] Smith G, Sawyer WMJ R , Morris R C. US 3 682 849 , 1982
[28] McCain J H , Theiling J L F. US 4 453 023 , 1984
[29] Reikichi W, Hiromutsu W. J . Am. Chem. Soc. , 1976 , 98(13) : 3764 —3768
[30] Shozo Y, Kazutomo T , Mitsuo O. Bull . Chem. Soc. Jpn. ,1977 , 50(6) : 1386 —1390
[31] Matheson K L , Cox M F. Rivista Italiana delle Sostanze Grasse ,1995 , 72(9) : 391 —395
[32] Sallay P , Morgos J , Farkas L , et al . Tenside Detergents , 1980 ,17(6) : 298 —300
[33] Ziegenhain W C , Jackson R T , Rose L. US 4 254 287 , 1981
[34] Yodhifa N N. JP 02 227 426 , 1991
[35] Johnston H R. US 3 278 459 , 1966
[36] 吴立传(Wu L C) , 余爱芳(Yu A F) , 张敏(Zhang M) 等.高分子学报(Acta Polymerica Sinica) , 2003 , (6) : 871 —874
[37] 颜再荣(Yan Z R) , 杨淑英( Yang S Y) , 余爱芳( Yu A F)等. 高分子通报(Polymer Bulletin) , 2001 , (5) : 1 —6
[38] 黄亦军(Huang Y J ) , 戚国荣(Qi G R) , 封麟先(Feng L X) .高分子学报(Acta Polymerica Sinica) , 2002 , (3) : 271 —275
[39] Pazos J F , Shih T T. US 5 689 012 , 1997
[40] 顾约伦( Gu Y L) . 高桥石化( Gao Qiao Petro-Chemical ) ,2004 , 19(6) : 55 —56
[41] Kim I , Ahn J T , Ha C S , et al . Polymer , 2003 , 44 : 3417 —3428
[42] Clement K S , Walker L L , Wehmeyer R M, et al . WO 0 104183 , 2001
[43] Webser O W. Science , 1991 , 251 (25) : 887 —892
[44] 黄梅(Huang M) , 胡耿源(Hu G Y) , 封麟先(Feng L X) . 高分子材料科学与工程( Polymer Materials Science & Engineering) , 1999 , 15(5) : 40 —44
[45] 董雅莉(Dong Y L) , 周新锐(Zhou X R) , 郑玉斌(Zheng Y B) 等. 日用化学工业( China Surfactant Detergent & Cosmetics) , 2005 , 35(1) : 36 —39
[46] 曹维孝(Cao W X) . 化学通报(Chemistry) , 1991 , (8) : 25 —29
[47] Aida T , Inoue S. Macromolecules , 1981 , 14(5) : 1166 —1169
[48] 黄梅(Huang M) , 陈关喜(Chen G X) . 浙江大学学报: 工学版(Journal of Zhejiang University , Engineering Science) , 2000 ,34(3) : 297 —300
[49] 于剑昆( Yu J K) . 黎明化工(Liming Chemical Industry) ,1997 , (3) : 8 —13
[50] 周立宏(Zhou L H) , 唐辉( Tang H) . 精细与专用化学品(Fine and Specialty Chemicals) , 2004 , 12(13) : 3 —5
[51] 胡富陶(Hu F T) , 房江华(Fang J H) . 分子催化(Journal of Molecular Catalysis) , 2001 , 15(5) : 388 —390
[52] Yamaguchi K, Ebitani K, Yoshida T , et al . J . Am. Chem.Soc. , 1999 , 121 (18) : 4526 —4527
[53] Braune W, Okuda J . Angew. Chem. Int . Ed. , 2003 , 42 : 64 —68
[54] Kozlovshii R A , Yushchenko V V , Kitaev L E , et al . Russian Chemical Bulletin , International Edition , 2002 , 51 (6) : 967 —974
[55] 王国平(Wang G P) , 张一烽(Zhang Y F) , 沈之荃(Shen Z Q) 等. 浙江大学学报(Journal of Zhejiang University) , 1988 ,22(1) : 67 —73
[56] 彭建德(Peng J D) , 张一烽(Zhang Y F) , 沈之荃(Shen Z Q) 等. 浙江大学学报(自然科学版) (Journal of Zhejiang University (Science Edition) ) , 1990 , 24(6) : 810 —816
[57] 曾宪标(Zeng X B) , 张一烽(Zhang Y F) , 张富尧(Zhang F Y) 等. 高分子材料科学与工程(Polymer Materials Science & Engineering) , 1999 , 15(4) : 30 —33
[58] Zheng Y S , Ying L Q , Shen Z Q. Polymer , 2000 , 41 ( 4) :1641 —1643
[59] Jacquier-Gonod V , Llauro M F , Hamaide T. Macromol . Chem.Phys. , 2000 , 201 (1) : 12 —20
[60] Nobori T , Suzuki T , Kiyono S , et al . EP 791 600 , 1997
[61] 于剑昆(Yu J K) . 聚氨酯工业(Polyurethane Industry) , 2004 ,19(5) : 10 —14
[62] Kouno M, Mizutani K, Nobori T , et al . EP 763 555 , 1997
[63] Nobori T , Hara R , Hayashi T , et al . JP 102330 387 , 1998
[64] Yamazaki S , Kunihiro T , Matsumoto S , et al . JP 031 689 , 2001
[65] Matsumoto S , Kunihiro T , Yamazaki S , et al . JP 089 487 , 2001
[66] Hayashi T , Hara R , Kiyono S , et al . JP 10 273 512 , 1998
[67] Shibahara A , Hara I , Kiyono S , et al . EP 1 044 982 , 2000
[68] Hayashi T , Funaki K, Shibahara A , et al . JP 11 302 371 , 1999
[69] Wehmeyer R M. WO 01P902 20 , 2001
[70] Peretti K L , Ajiro H , Cohen C T , et al . J . Am. Chem. Soc. ,2005 , 127 : 11566 —11567
[1] Bin Jia, Xiaolei Liu, Zhiming Liu. Selective Catalytic Reduction of NOx by Hydrogen over Noble Metal Catalysts [J]. Progress in Chemistry, 2022, 34(8): 1678-1687.
[2] Mingjue Zhang, Changpo Fan, Long Wang, Xuejing Wu, Yu Zhou, Jun Wang. Catalytic Reaction Mechanism for Hydroxylation of Benzene to Phenol with H2O2/O2 as Oxidants [J]. Progress in Chemistry, 2022, 34(5): 1026-1041.
[3] Shiying Yang, Danyang Fan, Xiaojuan Bao, Peiyao Fu. Modification Mechanism of Zero-Valent Aluminum by Carbon Materials [J]. Progress in Chemistry, 2022, 34(5): 1203-1217.
[4] Bolin Zhang, Shengyang Zhang, Shengen Zhang. The Use of Rare Earths in Catalysts for Selective Catalytic Reduction of NOx [J]. Progress in Chemistry, 2022, 34(2): 301-318.
[5] Bai Wenji, Shi Yubing, Mu Weihua, Li Jiangping, Yu Jiawei. Computational Study on Cs2CO3-Assisted Palladium-Catalyzed X—H(X=C,O,N, B) Functionalization Reactions [J]. Progress in Chemistry, 2022, 34(10): 2283-2301.
[6] Xuechuan Wang, Yansong Wang, Qingxin Han, Xiaolong Sun. Small-Molecular Organic Fluorescent Probes for Formaldehyde Recognition and Applications [J]. Progress in Chemistry, 2021, 33(9): 1496-1510.
[7] Changfan Xu, Xin Fang, Jing Zhan, Jiaxi Chen, Feng Liang. Progress for Metal-CO2 Batteries: Mechanism and Advanced Materials [J]. Progress in Chemistry, 2020, 32(6): 836-850.
[8] Guofu Qin, Yihuan Liu, Fan Yin, Xin Hu, Ning Zhu, Kai Guo. Grafting Modification of Lignin via Ring-Opening Polymerization [J]. Progress in Chemistry, 2020, 32(10): 1547-1556.
[9] Fanfan Du, Ying Zheng, Guorong Shan, Yongzhong Bao, Suyun Jie*, Pengju Pan*. Hydrogen Bonding-Based Non-Metallic Organocatalysts for Ring-Opening Polymerization of Lactones [J]. Progress in Chemistry, 2018, 30(6): 710-718.
[10] Han Gao, Jun Xu, Xin Hu, Ning Zhu, Kai Guo. Synthesis of Poly(Ester Amide) [J]. Progress in Chemistry, 2018, 30(11): 1634-1645.
[11] Chenhui Wei, Heyun Fu, Xiaolei Qu, Dongqiang Zhu. Environmental Processes of Dissolved Black Carbon [J]. Progress in Chemistry, 2017, 29(9): 1042-1052.
[12] Ming Ge, Zhenlu Li. All-Solid-State Z-Scheme Photocatalytic Systems Based on Silver-Containing Semiconductor Materials [J]. Progress in Chemistry, 2017, 29(8): 846-858.
[13] Shiying Yang, Yixuan Zhang, Di Zheng, Jia Xin. Surface Reaction Mechanism of ZVAl Applied in Water Environment:A Review [J]. Progress in Chemistry, 2017, 29(8): 879-891.
[14] Xiaojun Shen, Panli Huang, Jialong Wen, Runcang Sun. Research Status of Lignin Oxidative and Reductive Depolymerization [J]. Progress in Chemistry, 2017, 29(1): 162-178.
[15] Yao Zhen, Dai Boen, Yu Yunfei, Cao Kun. Thiol-Epoxy Click Chemistry and Its Applications in Macromolecular Materials [J]. Progress in Chemistry, 2016, 28(7): 1062-1069.