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Progress in Chemistry 2007, Vol. 19 Issue (01): 136-144 Previous Articles   Next Articles

• Review •

Ring-Opening Homopolymerization of Lactides

Yu Cuiping 1**;Li Xi1; Shen Zhiquan2   

  1. 1. Department of Chemical and Biochemical Engineering, Zhejiang University, Hangzhou 310027, China；2. Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China
  • Received: Revised: Online: Published:
  • Contact: Yu Cuiping
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Polylactides（PLA）, biodegradable aliphatic polyesters, are derived from renewable resources. Polylactides have unique physical properties that make them useful in many applications including packaging, paper coating, fibers, and films. The production and use of PLA at low costs and in large quantities will lessen the dependence on petrochemical greatly. High molecular weight PLA can be prepared by ring-opening polymerization of lactides. Three different classes of initiators or catalysts and reaction mechanisms for the ring-opening polymerization of lactides are summarized.Recent progress in the research of novel catalysts for the lactides polymerization is reviewed. In particular, the advantages of rare earth catalysts for the ring-opening polymerization of lactides are emphasized, and biological virtue of polylactides obtained by rare earth catalysts is discussed.
Key words: lactides, ring-opening polymerization, rare earth catalysts, biodegradable aliphatic polyesters

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