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Progress in Chemistry 2006, Vol. 18 Issue (10): 1270-1277 Previous Articles   Next Articles

• Review •

Tri-Reforming of Methane to Synthesis Gas

Hongtao Jiang1,2;Huiquan Li1**;Yi Zhang1   

  1. 1. The Key Laboratory of Green Process and Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100080, China; 2. Graduate School of the Chinese Academy of Sciences, Beijing 100049, China 
  • Received: Revised: Online: Published:
  • Contact: Huiquan Li
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Tri-reforming of methane is a novel process of methane reforming by carbon dioxide , steam , and oxygen simultaneously in one reactor. Tri-reforming of methane can not only produce synthesis gas with H2/CO ratio of 1.5 —2.0 but also mitigate or eliminate coke deposition of catalyst . It is fit for producing synthesis gas which can be used for production of chemicals (such as methanol and dimethyl ether) , and ultra-clean fuels (such as liquid hydrocarbons) at lower cost than current process of steam reforming of methane. In this paper , the progress in tri-reforming of methane to synthesis gas is reviewed , including thermodynamics , catalyst development , reactor and kinetic behavior. We also point out the favorable foreground of tri-reforming on synthetical utilization of flue gas , coal-bed methane and natural gas. In order to make the process of tri-reforming of methane to synthesis gas economically feasible , what still should be done are developing high-active and coke-resistant catalyst , improving reactor , and probing mechanism of reaction and kinetic behavior.
Key words: methane, tri-reforming, synthesis gas, coke deposition, catalysts

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Abstract

Tri-Reforming of Methane to Synthesis Gas