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Progress in Chemistry 2006, Vol. 18 Issue (10): 1253-1261   Next Articles

• Review •

Misfit-Layered Compounds

Yaohua Xu1**;Yuan Wang1,2;Jianing Xu1;Tianyou Song1;Shouhua Feng3**;Wenqin Pang3   

  1. 1. Department of Inorganic and Materials Chemistry,Chemistry College, Jilin University, Changchun 130012, China; 2. College of Materials and Chemical Engineering, Changchun University of Science and Technology, Changchun 130022, China; 3. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130012, China
  • Received: Revised: Online: Published:
  • Contact: Shouhua Feng
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The studies on the misfit layered compounds are reviewed. There are two subsystems with different unit cell dimensions in the misfit layered compounds,oxides and non-oxides. The chemical formula of non-oxides compounds can be written as [(MX)n]x(TX2)m (M=Sn, Pb, Bi, lanthanides；X=S, Se, Te；n=1，3/2，2; 1.08 ≤ x ≤ 1.23; T = transition elements；m=1, 2, 3.). The misfit layered oxides have the general chemical formula as Aα[(MO)n]x(TO2)m (A=Tl, Bi; M=Ca, Sr, Bi, Co; T=Co, Cr; α=0-0.41; n=1, 3/2, 2; m=1, 2; x is in relation with the components of the compounds). Misfit layered compounds including their classification , structures , synthetic methods and properties are summarized. The developing orientation in future is prospected.
Key words: two sublattices, misfit structure, layered compounds, oxides, sulfides, chalcogenides

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Abstract

Misfit-Layered Compounds