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Progress in Chemistry 2006, Vol. 18 Issue (09): 1092-1100 Previous Articles   Next Articles

• Review •

Progress in Porous Phosphonates

Zongbin Wu1; Peng Tian2**; Zhongmin Liu2;Zongqiang Mao1   

  1. 1. Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084, China;2. Natural Gas Utilization & Applied Catalysis Laboratory, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China  
  • Received: Revised: Online: Published:
  • Contact: Peng Tian
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Porous phosphonates are novel porous materials , which have drawn much attention in recent years. The derivable and variety of organophosphorus ligands endow the materials many special properties. The synthetic methods and their characters have been discussed. Precipitation method , melt method , hydrothermal method , solvothermal method ,and template-assisted method have been developed for synthesizing porous phosphonates. Following the principles of coordinate chemistry , these methods give many opportunities for synthesizing a desired structure. Besides the well-known pillared-layered structures and zeolite-type structures , novel tubular morphologies with layered frameworks have been reported recently in some diphosphonates. The tubular morphologies open a new strategy for obtaining porous phosphonates. Up to now , great efforts have been devoted to the porous phosphonates , however , only a few of these compounds are really porous. The removal of the template often leads to the collapse of the structures , which hinders the materials for going further. More works and new ideas should been applied to suppress their drawbacks. Some proposals concerning the key points for porous phosphonates have been presented in the article.
Key words: porous phosphonates, synthetic methods, porous character, tubular morphology

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Progress in Porous Phosphonates