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Progress in Chemistry 2006, Vol. 18 Issue (0708): 939-949 Previous Articles   Next Articles

• Review •

Synthesis and Applications of Polymer Molecular Brushes

Lei Zhang;Wen Li;Afang Zhang*   

  1. College of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450052, China
  • Received: Revised: Online: Published:
  • Contact: Afang Zhang
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This article highlights the recent development of synthesized polymer molecular brushes, which are formed by high-densely attaching polymers via different strategies to linear polymers, dendrimers or dendronized polymers. Three different synthetic methods for molecular brushes, e. g. “grafting through”， “grafting from” and “grafting to” are detailed and compared based on the achievable molar mass and structure perfection of the resulted molecular brushes, together with some conformation dependence. Some reports on the synthesis and conformational study of peptide brushes and thermally switchable polymer brushes were also included. The applications of molecular brushes in different areas, such as nano-materials for surface modification and nano-wires are also introduced briefly.
Key words: molecular brushes, polymerization, controlled radical polymerization, dendrimer

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[ 1 ] Milner S T. Science , 1991 , 251 : 905 —914
[ 2 ] Leduc M R , Hawker C J , Dao J , et al . J . Am. Chem. Soc. ,1996 , 118 : 11111 —11118
[ 3 ] Inoue K. Prog. Polym. Sci . , 2000 , 25 : 453 —571
[ 4 ] Schlüter A D. Top. Curr. Chem. , 1998 , 197 : 165 —191
[ 5 ] Halperin A , Terrell M. Adv. Polym. Sci . , 1992 , 100 : 31 —69
[ 6 ] Clayfield E J , Lumb E C. J . Colloid Interface Sci . , 1996 , 22 :269 —284
[ 7 ] Ito Y, Ochiai Y, Park Y S , et al . J . Am. Chem. Soc. , 1997 ,119 : 1619 —1623
[ 8 ] Ito Y, Park YS , Imanishi Y. J . Am. Chem. Soc. , 1997 , 119 :2739 —2740
[ 9 ] Ito Y, Nishi S , Park Y S , et al . Macromolecules , 1997 , 30 :5856 —5859
[10] Ito Y, Park Y S , Imanishi Y. Macromol . Rapid Commun. ,1997 , 18 : 221 —224
[11] Velten U , Shelden R A , Caseri W R , et al . Macromolecules ,1999 , 32 : 3590 —3597
[12] Velten U , Tossati S , Shelden R A , et al . Langmuir , 1999 , 15 :6940 —6945
[13] Pyun J , Kowalewski T , Matyjaszewski K. Macromol . Rapid Commun. , 2003 , 24 : 1043 —1059
[14] Zhao B , Brittain W J . Prog. Polym. Sci . , 2000 , 25 : 677 —710
[15] Zhang M, Müller A. J . Polym. Sci . , Polym. Chem. , 2005 , 43 :3461 —3481
[16] Pyun J , Kowalewski T , Matyjaszewski K. Macromol . Rapid Commun. , 2003 , 24 : 1043 —1059
[17] Matyjaszewski K, Xia J . Chem. Rev. , 2001 , 101 : 2921 —2970
[18] Kamigaito M, Ando T , Sawomoto M. Chem. Rev. , 2001 , 101 :3689 —3746
[19] Tsukahara Y, Mizuno K, Segawa A , et al . Macromolecules ,1989 , 22 : 1546 —1552
[20] Tsukahara Y, Tsutsumi K, Yamashita Y, et al . Macromolecules ,1990 , 23 : 5201 —5208
[21] Wintermantle M, Fischer K, Gerle M, et al . Angew. Chem. Int .Ed. , 1995 , 34 : 1472 —1474
[22] Wintermantle M, Schmidt M. Macromol . Rapid Commun. , 1994 ,15 : 279 —284
[23] Dziezok P , Sheiko S S , Fischer K, et al . Angew. Chem. Int .Ed. , 1997 , 36 : 2812 —2815
[24] Djalali R , Hugenberg N , Fischer K, et al . Macromol . Rapid Commun. , 1999 , 20 : 444 —449
[25] Ishizu K, Tsubaki K, Ono T. Polymer , 1997 , 39 : 2935 —2939
[26] Tsubaki K, Ishizu K. Polymer , 2001 , 42 : 8387 —8393
[27] Yamada K, Miyazaki M, Ohno K, et al . Macromolecules , 1999 ,32 : 290 —293
[28] Neugebauer D , Zhang Y, Pakula T , et al . Macromolecules ,2003 , 36 : 6746 —6755
[29] Chiefari J , Rizzardo E. Handbook of Radical Polymerization. New York : Wiley , 2002
[30] Neiser M W, Okuda J , Schmidt M. Macromolecules , 2003 , 36 :5437 —5439
[31] Neiser M W, Muth S , Kolb U , et al . Angew. Chem. Int . Ed. ,2004 , 43 : 3192 —3195
[32] Beers L K, Gaynor S G, Matyjaszewski K, et al .Macromolecules , 1998 , 31 : 9413 —9415
[33] Matyjaszewski K, Qin S , Boyce J R , et al . Macromolecules ,2003 , 36 : 1843 —1849
[34] Li C M, Gunari N , Fischer K, et al . Angew. Chem. Int . Ed. ,2004 , 43 : 1101 —1104
[35] You Y Z , Hong C Y, Pan C Y, et al . Adv. Mater. , 2004 , 16 :1953 —1957
[36] Bêrner H G, Duran D , Matyjaszewski K, et al . Macromolecules ,2002 , 35 : 3387 —3394
[37] Qin S H , Matyjaszewski K, Xu H , et al . Macromolecules , 2003 ,36 : 605 —612
[38] Zhang A F , Barner J , Gêssel J , et al . Angew. Chem. Int . Ed. ,2004 , 43 : 5185 —5188
[39] Grodzinski J J . Polym. Adv. Technol . , 2002 , 13 : 615 —625
[40] Balamurugan S S , Bantchev G B , Yang Y M, et al . Angew.Chem. , 2005 , 117 : 2 —5
[41] Leclerc M, Martinez F , Wegner G. Macromol . Chem. , 1989 ,190 : 3105 —3116
[42] Bêrner H G, Beers K, Matyjaszewski K, et al . Macromolecules ,2001 , 34 : 4375 —4383
[43] Cheng G L , Bêker A , Zhang M F , et al . Macromolecules , 2001 ,34 : 6883 —6888
[44] Zhang M F , Breiner T , Mori H , et al . Polymer , 2003 , 44 :1449 —1458
[45] Vosloo J , Tonge M P , Fellows C M, et al . Macromolecules ,2004 , 37 : 2371 —2382
[46] Zhang B , Fischer K, Schmidt M. Macromol . Chem. Phys. ,2005 , 206 : 157 —162
[47] Deming T J . Adv. Mater. , 1997 , 9 : 299 —311
[48] Dimitrov I , Schlaad H. Chem. Commun. , 2003 , 2944 —2945
[49] Higashi N , Koga T , Niwa N , et al . Chem. Commun. , 2000 ,361 —362
[50] Higashi N , Koga T , Niwa N , et al . Adv. Mater. , 2000 , 12 :1373 —1375
[51] Zhang A , Schlüter A D. Polym. Prepr. , 2003 , 44 : 524 —525
[52] Deffieux A , Schappacher M. Macromolecules , 1999 , 32 : 1797 —1802
[53] Schappacher M, Deffieux A. Macromolecules , 2000 , 34 : 4712 —4723
[54] Neugebauer D , Zhang Y, Pakula T , et al . Polymer , 2003 , 44 :6863 —6871
[55] Djalali R , Li S Y, Schmidt M. Macromolecules , 2002 , 35 :4282 —4288
[56] Mori H , Müller A H E. Prog. Polym. Sci . , 2003 , 28 : 1403 —1439
[57] Zhang M, Estournès C , Bietsch W, et al . Adv. Mater. , 2004 ,14 : 871 —882
[58] Kim H C , Wilds J B , Kreller C R , et al . Adv. Mater. , 2002 ,14 : 1637 —1639
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